734 



SUBJECT INDEX 



Globin native (contd.) 



electrometric titration, 255 



differential of globin and hemiglobin, 

 244 

 fate in hemogIol>in breakdown, 548, 568 

 frictional ratio, 250 

 isoelectric point, 255 

 molecular weight, 250 

 oxidation, in autoxidation of hemo- 

 globin, 390 

 in denaturation, 395, 478 

 preparation, 258 



specificity, 321. See also Hemoglobin. 

 synthesis in vivo, 610 

 Glutathione 



as anticatalase, 412 



and choleglobin formation, 477, 478, 



517 

 and dehydroascorbic acid, 470, 517, 518 

 in erythrocyte, 516, 522, 619 

 and hem/globin, 522 

 as substrate of cytochrome c, 376 

 Glycine, in porphyrin s\nthesis, 637 

 Gmelin reaction, 109, 112 (table), 116, 138 

 Green hemins, 201, 456, 490. See also 

 Chlorophyll hemins, Pheophorbide 

 kemin, Verdochemochrome. 

 Green hemoglobins, 455, 489. See also 

 Choleglobin, Pseiidohemoglobin, Cru- 

 oralbin, Snlf hemoglobin, Pheophor- 

 bide-h hemoglobin, Verdohemoglobin. 

 formation of, and perturbation, 489, 

 490 

 Green pigment. See Choleglobin {"green 



pigment"). 

 Green-red hemins, 201, 650. See also 

 Spirographis hcmin, Pheohemins. 



H 



Haldane effect, 217, 271 



HCl number. See also Porphyrins. 



of bile pigments, 115 

 Heinz bodies, 525, 527, 528 

 Helicorubin, 225, 654 

 Hemaffine groups, 231 

 Hemalbumin, 225, 243 



carboxyhemalbumin, 243 



linkage of heme to albumin, 243 

 Hematin compounds 



biological role, 2, 6 



catalatic action, 402 



detection as hemochromes, 176 



distribution, 343 



Hematin compounds (contd.) 



green. See Green hemins. 



green-red. See Green-red hemins. - 



iron, removal from, 167 



magnetochemistry, 160 



nomenclature, 163, 164 (table) 



oxidation-reduction potential, 193 ff., 

 194 (table) 

 influence, of ;^H on, 197 

 of buffer anions, 201 



oxidative action, 341 



peroxidative action, 402 



reaction with O^ and H^Os, 184 



red, 201 



surface properties, 70, 172 



valency change, 6 

 Hematin, 164 (table), 169 



absorption spectra, 172, 173 (table) 



acid hematin, 170-172, 173 (table) 



"acid hematin" from hemoglobin, 223, 

 228 (table), 256, 296, 300 



alkaline hematin, 169 ff., 173 (table) 



"alkaline hematin" from hemoglobin, 

 223 



|3-hematins and «//-hematins, 171, 172 



in blood extravasations, 574 



borate compound, 172, 201 



catabolism, 575 



cyanide compounds, 187 ff. See also 

 Cyanide {hematin compouds). 



free cell hematin, 653 



as growth factor, 608, 654 



hydroxyhemin, 170, 171 



iron. See Iron, 



magnetochemistry, 160, 161, 173 



in malarial cell, 574 



polymerization, 171, 172, 194 



Schumm's test, 243, 574 



toxicity, 534, 577 

 Hematin c, 203, 488, 489, 599 

 Hematinemia, 574. See also Methemal- 



bumin. 

 Hematobiliverdin, 459 

 Hematohemoglobin, 239, 496 

 Hematoidin, 503, 545 

 Hematoma, 505, 574. See also Bile 



pigment formation (extrahepatic) . 

 Hematoporphyrin, 47, 48, 51 (table), 61, 

 69 (table) 



from cytochrome c, 350 



occurrence, 61 



synthesis, 56 



