153 



Alicylic Compounds (Non-terpenoid) 



Penicillium glaucum, P. purpurogenum 

 Nadine Wijkman, Ann. 485 61 (1931). (Isolation) 

 Kurt Kraft, ibid. 530 20 (1937). (Structure) 

 Matao Takashima, Akira Kitajima and Kenichi Otsuka, 

 Nippon Nogei-kagaku Kaishi 29 25 (1955). (Isolation from 

 P. purpurogenum) (Chem. Abstr. 52 20379d) 



318 Fumagillin (Amebacilin, Fumidil) C26H34O7, colorless or pale 

 yellow crystals, m.p. 189-194° (dec), [aln"' -26.6° (c 

 0.25 in methanol). 



CH2 



O CH3 



-CH— CH2— CH=C 



CH3 



CH3 



OCH3 



O 



I 



o=c- 



Aspergillus fumigatus Fres. 



J. Landquist, /. Chem. Soc, 4237 (1956). 



J. McNally and D. Tarbell, /. Am. Chem. Soc. 80 3676 

 (1958). 



D. Chapman and D. Tarbell, ibid. 80 3679 (1958). 



A. Cross and D. Tarbell, ibid. 80 3682 (1958). 



R. Carman, D. D. Chapman, N. J. McCorkindale, D. S. 

 TarbeU, F. H. L. Varino, R. L. West and D. L. Wilson, /. Am. 

 Chem. Soc. 81 3151 (1959). 



D. S. TarbeU, R. M. Carman, D. D. Chapman, K. R. Huff- 

 man and N. J. McCorkindale, J. Am. Chem. Soc. 82 1005 

 (1960). (Structure) 



T. E. Eble and F. R. Hanson, Antibiotics and Chemotherapy 

 1 54 (1951). (Isolation) 



