463 Indoles 



Psilocybe mexicana Heim, P. caerulescens Murr. var. 

 Mazecotorum Heim, P. aztecorum Heim, P. sempervirens 

 Heim et Cailleux, P. zapotecorinn Heim, Stropharia cuhen- 

 sis Earle 



A. Hofmann, R. Heim, A. Brack and H. Kobel, Experientia 

 14 107 (1958). 



A. Hofman, A. Frey, H. Ott, Th. Petrzilka and F. Troxler, 

 ibid. 14 397 (1958). (Synthesis) 



938 Gliotoxin ( Aspergillin ) , Ci:^Hi403NoSo, m.p. 195° (dec), [aW-' 

 -290° ±10° (c 0.078 in ethanol). 



/ 



s 



O 



CH3 

 CH2OH 



Trichoderma viride, Aspergillus fumigatus, Penicillium 

 terlikowski Zaleski, P. cinerascens, P. jenseni, Gliocladium 

 fimbriatuTn 



The yield of gliotoxin and its acetate from P. terlikowski 

 Zaleski was reported as about 100 mg. per liter. 



John R. Johnson, William F. Bruce and James D. Dutcher, 

 J. Am. Chem. Soc. 65 2005 (1943) and other papers in this 

 series. 



Malcolm R. Bell, John R. Johnson, Bernard S. Wildi and 

 R. B. Woodward, J. Am. Chem. Soc. 80 1001 (1958). (Struc- 

 ture) 



939 Gliotoxin Acetate, Ci-.HieO-NoS^, pale yellow rhombic crystals, 

 m.p. 159°, [a]i,''' -197° (c 0.600 in chloroform). 



^N 



O 



O^^CH3 



CH2— O— C— CH3 



Penicillium terlikowski Zaleski 



John R. Johnson, Aklaq R. Kidwai and John S. Warner, /. 

 Am. Chem. Soc. 75 2110 (1953). 



