Relative intensity % 
PEAK 1 80: PEAK 2 
20 
i ir | Lh | t T T T 
100 200 300 200 300 
me me 
SCOPOLAMINE 
o 124 H.—CH-CH, ATROPINE i) 2 94 . va 
CH; ee | j : 
| em H,0H j CH 38 
re CH,—CH—CH, i bs e f CH—CH—CH, { ee iS 
> 60: 1 me = 60- q| lon 
} CH-CH, j CH—¢H— H; + M=303 
i a M = 289 . 
g 40+ Ne” Q i + | 
i : CH,—CH—-CH, 154 
bu, 2 | ca? bea | AACR, 
ao : CH,—CH—CH, f Ccrsh N CHO M+=303 
| | 140 M*= 289 CH—CH—CH, 
j i 2 
4. i adi. bk Lub | ' { + yi i | 
100 200 300 200 300 
mie mie 
Upper panel: mass spectra of compound in effuent from peak 1 and 2 from alkaloid fraction (Plate VIII). 
Lower panel: mass spectra of reference compounds. Conditions: see Experimental. 
ALY Ig 
XI 
