208 VEGETABLE MUCILAGE. 



It is characterized by crystallizing in spheero-crystals, by its be- 

 haviour to water and alcohol (dissolves in 27 parts of cold, and 

 easily in warm water, in 1040 of cold 96 per cent, spirit, and 

 800 of boiling 98 per cent), by its power of dissolving oxide of 

 copper, and by yielding leucic acid when acted upon by nitrous 

 acid. 



1 have already directed attention to the identity of the cheno- 

 podine obtained from decomposing yeast with leucine.^ Gorup 

 Besanez has made the same assertions of the chenopodine from 

 Chenopodium album. 



Tyrosine, as well as leucine, has lately been detected in plants, 

 especially in germinating seeds.- Aqueous extracts of the material 

 under examination are concentrated, precipitated with alcohol, 

 filtered, freed from alcohol by distillation, evaporated to a syrup, 

 and allowed to stand, when the tyrosine separates out in groups 

 of warty crystals. By recrystallization from ammoniacal alcohol 

 it may be obtained in acicular crystals. Solutions of the latter 

 develop a rose-colour with mercuric nitrate and a little nitrous 

 acid. Warmed to 50° with concentrated sulphuric acid (half-hour), 

 and saturated Avith carbonate of barium, it yields a mass which 

 assumes a fine violet with ferric chloride. 



Puitanhin agrees with tyrosine in most of its reactions, especially 

 the two just described. It is almost insoluble in cold water, 

 alcohol and ether, sparingly soluble in boiling water, but freely in 

 ammonia. Suspended in water, and then warmed with a little 

 nitric acid, it dissolves, passing, as it does so, from rose to ruby- 

 red and blue, turning finally green with red fluorescence. ^ 



VEGETABLE MUCILAGE. 



§ 193, Vegetable Mucilage, Pectin, etc. — The substances desig- 

 nated by these names are a source of much inconvenience to the 

 analyst, due probably to their occurring in various modifications 



^ Compare Bergman, 'Das putride Gift,' Dorpat Gläser. See also Reinsch, 

 N. Jahrb. f. Pharm, xxvii. 123, 1867. 



2 Compare Schulze and Barbieri, Ber. d. d. chem. Ges. x. 199, xi. 710 

 (Joum. Chem. Soc. xxxiv. 663). 



ä It is notorious that ratanhin does not occur in rhatany-root, and that its 

 presence in certain samples of commercial extract of rhatany is due to adultera- 

 tion. Compare also Kreitmair, Jahresb. f. Pharm. 136, 1874 (Year-book 

 Pharm. 90, 1875). Gintl believes ratanhin to be identical with angelin from 

 Ferreira spectabilis (Zeitschr, d, österr. Apoth, Ver. 32, 1869). 



