Book I. VEGETABLE CHEMISTRY. 223 



lies. And from the action operated upon by acids it is thought to be composed of carbon, hydrogen, 

 oxygen, and azote. It seems to exist in a great variety of plants combined with other ingredients. It 

 may be separated from resins by alcohol. It may be separated from the berries of the misseltoe by means 

 of water, and from other vegetable substances by other processes. It is said to be contained both in opium 

 and in mastic. But from these substances it cannot be extracted in sufficient quantities to make it worth 

 the labor. It is applied to a great many useful purposes both in medicine and the arts, to which, from 

 its great pliability and elasticity, it is uncommonly well adapted. In the countries where it is produced 

 the natives make boots and shoes of it, and often use it by way of candle. 



1465. Cork. The substance known by the name of cork is the outer and exfoliated bark of the quercus 

 suber or cork-tree, a species of oak that grows in great abundance in France, Spain, and Italy. But to 



{)revent its natural exfoliation, which is always irregular, and to disengage it in convenient portions, a 

 ongitudinal incision is made in the bark from the root to the top of the stem; and a transverse and cir- 

 cular incision at each extremity. The outer layer, which is cork, is then stripped off, and to flatten and 

 reduce it to sheets it is put into water and loaded with weights. The tree continues to thrive, though it 

 is thus stripped of its cork once in two or three years. Cork is a light, soft, and elastic substance, dis- 

 tinguished by the following properties : Its color is a sort of light tan. It is very inflammable, and 

 burns with a bright white flame, leaving a black and bulky charcoal behind. When distilled it yields a 

 small quantity of ammonia. Nitric acid corrodes and dissolves it, changing its color to yellow, and finally 

 decomposes it, converting it partly into an acid, and partly into a soft substance resembling wax or resin. 

 The acid which is thus formed is denominated the suberic acid, and has been proved by the experiments 

 of Lagrange to be an acid of a peculiar nature. It seems probable that cork exists in the bark of some 

 other trees also, as well as the quercus suber. The bark of the ulmus suberosa assumes something 

 of the external appearance of cork, which it resembles in its thickness, softness, and elasticity, and in its 

 loose and porous texture, as well as also in its chemical properties. Fourcroy seems, indeed, to regard the 

 epidermis of all trees whatever to be a sort of cork, but does not say on what grounds his opinion is 

 founded. * 



1466. Woody fibre. The principal body of the root, stem, and branches of trees, is designated by the 

 appellation of wood. But the term is too general for the purpose of analytical distinction, as the part 

 designated by it often includes the greater part of the substances that have been already enumerated. It 

 remains, therefore, to be ascertained whether there exists in the plant any individual substance different 

 from those already described, and constituting more immediately the fabric of the wood. If a piece of 

 wood is well dried and digested, first in water and then in alcohol, or such other solvent as shall produce 

 no violent effects upon the insoluble parts ; and if the digestion is continued till the liquid is no longer 

 colored, and dissolves no more of the substance of the plant, there remains behind a sort of vegetable 

 skeleton, which constitutes the basis of the wood, and which has been denominated woody fibre. It is 

 composed of bundles of longitudinal threads, which are divisible into others still smaller. It is somewhat 

 transparent. It is without taste and smell, and is not altered by exposure to the atmosphere. It is inso- 

 luble in water and alcohol ; but the fixed alkalies decompose it with the assistance of heat. When heated 

 in the open air it blackens without melting or frothing, and exhales a thick smoke and pungent odor, 

 leaving a charcoal that retains the form of the original mass. When distilled in a retort it yields an em- 

 pyreumatic oil, carburetted hydrogene gas, carbonic acid, and a portion of ammonia, according to Four- 

 croy, indicating the presence of nitrogen as constituting one of its elementary principles ; and yet this 

 ingredient does not appear in the result of the later analysis of Gay Lussac and Thenard, which is, car- 

 bon, 52-53; oxygen, 41-78; hydrogen, 5-69; total 100. 



1467. Charcoal. When wood is burnt with a smothered flame, the volatile parts are driven off by 

 the heat, and there remains behind a substance exhibiting the exact form, and even the several layers of 

 the original mass. This process is denominated charring, and the substance obtained, charcoal. As it is 

 the woody fibre alone which resists the action of heat, while, the other parts of the plant are dissipated, it 

 is plain that charcoal must be the residuum of woody fibre, dnd that the quantity of the one must depend 

 upon the quantity of the other, if they are not rather to be considered as the same. Charcoal may be ob- 

 tained from almost all parts of the plant, whether solid or fluid. It often escapes, however, during com- 

 bustion, under the form of carbonic acid, of which it constitutes one of the elements. From a variety of 

 experiments made on different plants and on their different parts, it appears that the green parts contain 

 a greater proportion of charcoal than the rest. But this proportion is found to diminish in autumn, when 

 the green parts begin to be deprived of their glutinous and extractive juice. The wood contains more 

 charcoal than the alburnum, the bark more than both. But this last result is not constant in all plants, 

 because the bark is not a homogeneous substance, the outer parts being affected by the air and the inner 

 parts not. The wood of the quercus robur, separated from the alburnum, yielded from 100 parts of its 

 dried substance 19.75 of charcoal ; the alburnum, 17.5 ; the bark, 26 ; leaves gathered in May, 80 ; in 

 September, 26. But the quantity of charcoal differs also in different plants, as well as in different parts 

 of the same. According to the experiments of Mushet, 100 parts of the following trees afforded as 

 follows : 



Lienum viUe - - 26*8 



Mahogany .... 25-4 



Laburnum . - - - 24-5 



Chestnut 23-2 



Oak 22-6 



American black birch . - 21-4 



Walnut 206 



Holly 19-9 



Beech 19-9 



American maple .... 19'9 



Kim 19-5 



Norway fir - . - - 19-2 



Sallow 18-4 



Ash ...... 17.9, 



Birch - .... 17.4 



Scotch pine ..... 16.4 



1468. The propertks of charcoal axQm&o\nh\Y\ty \nyfrsA,eXy of -whXch, however, it absorbs a portion when 

 newly made, as also of atmospheric air. It is incapable of putrefaction. It is not altered by the most 

 violent heat that can be applied, if all air and moisture are excluded; but when heated to about 800 it 

 burns in atmospheric air or oxygene gas, and if pure, without leaving any residuum. It is regarded by 

 chemists as being a triple compound, of which the ingredients are carbon, hydrogene, and oxygene. 

 Charcoal is of great utility both to the chemist and artist as a fuel for heating furnaces, as well as for a 

 variety of other purposes. It is an excellent filter for purifying water. It is a very good tooth-powder ; 

 and is also an indispensable ingredient in the important manufacture of gunpowder. 



1469. The sap. If the branch of a vine is cut asunder early in the spring, before the leaves have begun 

 to expand, a clear and colorless fluid will issue from the wound, which gardeners denominate the tears of 

 the vine. It is merely, however, the ascending sap, and may be procured from almost any other plant by 

 the same or similar means, and at the same season ; but particularly from the maple, birch, and walnut- 

 tree, by means of boring a hole in the trunk. It issues chiefly from the porous and mixed tubes of the 

 alburnum ; though sometimes it does not flow freely till the bore is carried to the centre. A small branch 

 of a vine has been known to yield from twelve to sixteen ounces, in the space of twenty-four hours. A 

 maple-tree of moderate size yields about 200 pints in a season, as has been already stated ; and a birch- 

 tree has been known to yield in the course of the bleeding-season, a quantity equal to its own weight. In 

 the sap of fagus sylvatica, Vauquelin found the following ingredients : Water, acetate of lime, with ex- 

 cess of acid, acetate of potass, gallic acid, tannin, mucous and extractive matter, and acetate of alumina. 

 In 1039 parts of the sap of the ulmus campestris, he found 1027 parts of water and volatile matter, 9*240 of 

 acetate of potass, 1-060 of vegetable matter, 0-796 of carbonate of lime, besides some slight indications of 

 the presence of sulphuric and muriatic acids ; and at a later period of the season he found the vegetable 

 matter increased, and the carbonate of lime and acetate of potass diminished. From the above experi- 

 ments, therefore, as well as from those of other chemists, it is plain that the sap consists of a great 

 variety of ingredients, differing in different species of plants ; though there is too little known concerning 

 it to warrant the deduction of any general conclusions, aa the number of plants whose sap has beea hither- 



