>:2 CHEMICAL PROCESSES IN THE PLANT. 



Sulphur, a constituent of albuminoids, of allyl, and of the essential oil of 

 mustard, is taken up in the form of soluble salts of sulphuric acid, and chiefly 

 (or perhaps always) of calcium sulphate. This salt is probably, as Holzner first 

 pointed out\ decomposed by the oxalic acid which is formed in the plant itself, and 

 the insoluble calcium oxalate is thus formed, while the sulphuric acid parts with its 

 sulphur to the organic compounds which have been mentioned. 



Iron'^ (often accompanied by very variable quantities of Manganese) is indis- 

 pensable for the production of the green colouring substance of chlorophyll, as is 

 shown by experiments on vegetation; and since the green organs which contain 

 chlorophyll assimilate organic substances out of water and carbon dioxide, the 

 importance of this element for the life of the plant is very evident, although 

 extraordinarily small quantities of it are sufficient for this purpose. It may be taken 

 up by the plant in the form of the chloride or sulphate or of some other 

 compound. If larger quantities of solutions of iron become distributed through 

 the tissues, the cells quickly die. Although small quantities of iron are essential 

 for producing the green colour of chlorophyll, it is nevertheless uncertain whether 

 the green colouring substance itself contains iron as an integral constituent of its 

 chemical formula. 



Potassium is as essential for the assimilating activity of chlorophyll as iron for 

 its production. Nobbe^ has recently shown that if food-materials otherwise com- 

 plete but possessing no potassium are supplied to plants (as buckwheat), they 

 behave as if they were absorbing only pure water instead of the solution of food- 

 material. They do not assimilate and show no increase in weight, because no 

 starch can be formed in the grains of chlorophyll without the assistance of 

 potassium. The chloride is the most efficacious form in which potassium can 

 be offered to buckwheat ; the nitrate comes next to it. If the potassium is offered 

 only in the form of sulphate or phosphate, a very evident want of health is apparent 

 sooner or later, which results from the starch which is formed in the grains of chloro- 

 phyll not passing into the growing organs and thus becoming available for purposes 

 of vegetation. Sodium and Lithium cannot replace potassium physiologically, be- 

 cause the former is simpl^ useless to the plant, while the presence of the latter in 

 the cell-sap is injurious to the tissues. 



Phosphorus, Chlorine, Sodium, Calcium, and Magnesiinn, have, as far as is yet 

 known, no definite relation to special physiological purposes. The constant occur- 

 rence however of compounds of phosphoric acid in company with albuminoids, as 

 well as of potassium salts in organs containing starch and sugar, points towards 

 definite relations which they may possess to those chemical processes that imme- 

 diately precede the processes of construction in plants. A large part of the calcium 

 taken up by plants is, as has been mentioned, precipitated by oxalic acid, and 



^ Holzner, Ucber die Bedeutung des oxalsauren Kalkes, Flora 1867. — Hilgers, Jahrb. fiir wiss. 

 Bot, vol. VI, p. I. 



^ For special proof of the importance of iron see my Handbuch der Experimental-Physiologie, 

 p. 142. 



^ Nobbe, Schroder, and Erdmann, Ueber die Organische Lei:.tung des Kaliums in der Pflanze ; 

 Chemnitz, 1871. 



