Convcrsioji of Bc^izol-PJioiol. 7 



appearance similar to those already described. Water was 

 formed in abundance and the reaction -mass was dark-green 

 in color. The bases were separated by the method used with 

 isobutyl-phenol. 



Phenisamylaviiiie : — 



Nf-H =CnHi5.NH2, 



\ 



H 



a dark-brown oil of weak basic character, boiled at 2$g°-262°. 

 The distillation was continued until the temperature had 

 reached 266°, when only a small amount of carbonized sub- 

 stance remained. It seems probable that the oil distilling 

 between 259°-262° is identical with the amido-amyl-benzol 

 prepared by Calm.^ by the action of chlor-zinc-aniline upon 

 fermentation amylic alcohol, of which the boiling point is 

 given at 2 56°-2 58°. It gave upon analysis the following 

 results : — 



0.1547 gr. substance gave 0.4566 gr. carbon dioxide and 

 0.1415 gr. water, equal to 0.12453 gr. C. and 0.01572 gr. H. 



Calculated for 

 CiiHi,N. Found. 



Cii — 132 — 80.98 per cent .... 80.50 per cent. 

 Hi7- 17- 10.43 " • • • • 10.16 

 N - 14- 8.59 " 



163 — 100.00 per cent. 



Diphenisamylaminc : — 



/C6H4 . C5H11 

 NfQH^.QHu^QsHsoNH 



was obtained as a thick dark-brown oil, which boiled at 301°- 

 325°. In order to purify it, it was twice distilled with super- 

 heated steam, then in an atmosphere of hydrogen, when an 

 almost colorless oil distilled over between 3i9°-32i°. 



1 Berichte der Deutschen chem. Gesellschaft XV., 1643. 

 103 



