177 



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OCX) -^ 









































^ re 

 re -2 oo 



























































< 









< 















fcj J- o 



















C£i 









^ 



















< 















S 









^ 



<u 













nergy and 1.5 

 groups listed 



ted moleculai 

 species. 





o 



B 



re 



c 



3 















C 



re 



xi 



CO 



CO 



B 









T— 1 

 fl 



re 



X! 

 — 



■4— » 



B 



o 

 E 

 •22 

 re 

 Q 

 '^ 







s 

 2 



CO 



E 



_2 





" ^5 ? re 





re 























t/2 



B 

 o 



B 



2 







B 



re 

 O. 



<u 



x: 



IS 



CO 



collision 



function 



^ proto] 



molecul 





_re 













< 



<u 



a, 



B 

 JS 









<U 



a. 



B 

 (U 







3 



re 

 -a 



B 



1/2 



re 

 o 

 ■*— ' 



c/2 

 O 



15 eV. 

 aining 

 M-hH 

 acted 





g 













^ 



^ 









^ 



.2 







E 



re 



E 





re 



re 





re 







T— 1 



c 

 re 



o 

 re 









l-> 



o 



re 



kN 



re 

 > 







o 



E 

 X 



2^ 



7^ C CU 1/2 





j= 



Q 



re 



Q 



re 





x; 



Q 



re 



< 





Q 



re 







< 



re 





V2 



(N 



Q 



(N 



Q 





c/2 



rj 



Q 





rsi 



Q 







fti 



■4—1 



1/2 

 O 



E 



and m/z 

 90-100% 



t/i o *^ re 

 c c/3 a> e 





in 



C 



1-H 



+1 



C 



+1 





CO 



B 



+1 



^ 





B 



1— 1 



+1 









•i: E aJ 5 





_(/2 



re 



^ 



re 



-* 





CO 



re 



^ 



^H 





re 



'S- 







<u 



ondi 



ipoui 



on w 



prol 





C 



■^ 



<4-i 



-C 



M-i 





C 



^ 



<.hH 



B 



re 





4= 



<4-l 







B 



re 



x; 





.2 



t/2 



O 



CO 

 CO 



o 





.2 



CO 



o 



.& 





1/2 

 1/2 



o 



CO 





-B 

 4— ' 



o 



3 



-a 

 o 

 k. 



S^ - 



:s/MS c^ 



40 com 

 [nentati 

 M-H]- 





*-• 

 c 



re 



_4J 



CO 



<U 



(/3 

 CO 



o 



CO 



m 



CO 

 CO 



55 

 osses le 



(U 

 1/2 



CO 



U 



z 



c 



!U 



re 



ii 



to 

 <U 



CO 

 CO 



o 



1/3 



<u 



CO 

 1/2 



CO 

 CO 



r- 



— 

 CO 



1/2 

 1/2 



o 



CO 



<U 



CO 



C/1 



B 

 4J 



E 

 to 



re 



Ui 



z 



CO 



to 



■*-» 

 re 



at m/z ; 

 er ion a 



5 under M 



data from 



d for fragi 



and the 





emaining 



y at m/z 5 



"re 



3 

 <U 



c 



"re 



hi 



■4-^ 



3 

 (U 



B 



> 



ly at m/z 

 neutral 1 



"re 

 )-i 



3 

 1) 



C 



lU 



> 



■a 

 <u 



o 



emaining 

 y at m/z 5 



"re 

 1-1 



3 

 B 



"re 

 -^- 



3 

 <U 



B 



lU 

 > 



B 



_o 



B 

 <U 



k. 



re 



»/~i 



B 



re 



"re 



3 

 U 



B 



"re 



3 

 U 

 B 



> 



N 



"e 



XJ 



■a 

 <u 



E 

 I-I 

 o 



re 

 Q 



o 



to 



re 

 Q 

 o 



ghter ions 

 31 daught 



sristics of compound classe; 



Table consists of MS/MS 



by methane CI and selecte 



stracted molecular species, 



a> 



b* ^ 



^7i 



c^ 



s usual 

 f small 



'to 



(4-1 



^ ^ 



1*^ 



'!^ 



D- 





^ 



'iJ2 



_o 



'*^ 



1/2 



<j-i 



re 

 re 



U 



fthe 

 usua 



re 



E 



1/3 



CO 



U 



o 



3 



CO 



(U 



o 

 o 



3 



c 

 1 



fthe 

 usua 



re 



E 



CO 



CO 



<u 

 o 

 o 



3 



4J 



-B 

 ■*-» 



"re 

 3 



CO 



3 



re 

 E 



<4-l 



1/2 



u 



O 

 O 



3 



I-I 



o 



M— 1 



B 



.2 

 1 



"re 



O 



CO 



<U 



CO 



to 



ce of dau 

 ce of m/z 





o 



c/3 



o 



Base peak 

 Absence o 



O 



X 



1 





o 



D 

 O 



B 



CO 



X3 



< 



1/2 



<4-l 



o 



O 



re 



o 



<U 



o 



B 

 <U 



CO 



X 



< 



CO 



o 



a 



X 



1 



3 

 (U 



C3 



_o 



Intensi 

 Base p 

 Abseni 



CO 



on 



CO 



(U 



on 



o 

 Z 



Intensi 

 Base p 



1/2 



(U 



on 



i« 



B 



B 



CO 



re 



CQ 



CO 



'k- 



on 



re 



> 



Cu 



o 

 Z 



"re 



E 



on 



"re 



3 

 <U 



Z 



Presen 

 Presen 











































+ 







+ 





1 



+ 







+ 











1 



+ 







Parent 

 Ion 



X 

 -1- 







X 



1 





X 



X 



-1- 







1 











X 



1 



X 

 + 







■S ^ T3 ^ 

 ^ « Ji « 



S 







S 





S 



S 







S 











s 



S 







' ' 







> * 





> ' 



> * 







> ' 













' 1 







fc- o c <u 









































re e i-i 73 









































-2 Ch 

 ollisioi 

 ions fo 

 " hydri 



-a 



c 



(U 



I-I 



o 













§ 



















CO 







3 



o 



«: E 

 <u 



c/0 



c 

 o 



re 

 u 











C/2 E 



CO 



B 

 O 

 X) 



k> 



re 

 o 























Table 4 

 in the c 

 Parent 

 [M-H]- 



Comp 

 Class 



Aiken 

 (10 or 











Alkan 

 (10 or 

















(U 

 T3 



< 







