32 B. B. JEnEUIKHHt. 



MOHCHO npHHflTi, He n3MiHflK)iii,eHca OTT, Toro, <i>HJibTpyeTCfl JiH qjiCTaa BO^a iijih pacTBop^.)• 

 TaKnMT> o6pa30Mi> nMteMT>: 



^j; = Po{l-JhaB)-F^ ^Yl) 



Ho nocjit Toro Kam, OAHOCTopoHHig Bo;^Hbra toktj yciaHOBHJica repeal) cocjAt iv = v ; 

 CTfeAOBaxejiLHO no (V) h (VI), HMieMi, CJit^yiomee ypaBeenie AJia onpoA'fe.'ieHia P^. 



Ppd— ^.aeg) — Py P^ — Pq (1 — 7ia^) 



a a 



OTKyAa: 



P„ = 



Pod— 7itai?)-t-Po(l — ;taA) _ Pi-t-Pj? 



a; 2 2 



Pq [2 — (/^gg-t-feail] p (■[ /<ittJ-t-/taA \ CVII') 



noACTaBBBT. BbipaateHie a-ia Pj. nat ^opaiyjibi VII bi> ^opmyjiy (V), HJiteMi) cjitAywinee 

 BbipajKenie ^Jifl CKopocTH BtixoajAeHia hchakocth h3t> cocy^a: 



IlM'feH btj BHAy, 1T0 Pq Bi. Hamefi ^opMyji-fe ecit ocMoxnqecKoe ^aBJieHie BBiqacieHHoe (aa 

 ocHOBaHin 9KcnepHMeHTajii>HLixt AaHHbixi.) nai «>opMyjibi van't Hoff h Arrhenius'a (Nernst, 

 Theoretische Chemie 1900r., cxp. 349 — 351): Po = P [1 -h (w— 1)^], r^i ^ — cxe- 

 neHb AHCC0ii,ian,iH 3JieKTpojiHTa, m[3 — qncjio Iohobx, na Koxopbie pasjiaraexca ajieKxpoJiHii) 

 (6yKBbi *opMyjbi HSM'feHeHbi), a xaKace xo, ixo P=GTx const., rjifk G ecxb K0Hu;eHxpau,ia 

 pacxBopa, a T — a6cojiioxHaa xejinepaxypa, noiyqHMX> cjiifeAyiomee OKonqaxe-HbHoe Bbipaffieaie 

 AJia CKopocxH BbixoAa hchakocxh h3% cocy^a, noKasbiBaromee eaBHCHMOCXb ea oxxi KOHU,eHxpaniH 

 pacxBopa Bx> cocyjifk, xeMnepaxypbi, npoHHAaeMOCXH nepenonoKx. A vi B A-na pacxBopennbixx. 

 Ben],ecxBXj n AHCcon,ian,iH pacxBopeHHaro semecxBa: 



v = ^.^[lMm-m ( V^i^) (IX) 



Ko3<i>*Hu,ieHxi (p = const. 



Hax. *opMyjibi (IX) bhaho, qxo xoxa CKopocxb BbiA'feJieHia boabi H3x> cocyAa v pacxexX) 

 noAoSeo ocMoxnqecKOMy AaBJieaiio nponopn,ioHajibHO KOHneaxpauin pacxBopa, oaa naMtHaexca 

 oxx, xemnepaxypbi ropasAO 6bicxpie ocMOxnqecKaro AaBjenia, xaKT> KaKi corjiacao AaaHbiMX. 

 Bbime UHxnpoBaHHOH paSoxbi Rysselberghe'a npoHHu;aeMocxb nepenoHKH AJia pacxBopeaabixX) 

 BemecxBi pacxexi ct> xeiunepaxypoii ropasAO Sbicxp-fee ocMOxaqecKaro AaBJieaia. 



