10 B. KypHJiOBA. 



Kor^a oOmafl saKOHHOCXb iioji,TBepyKA<'"a xoth h'£cko.'ii>khmh npHMf.paMH, h noTOMy bt, Bwcmefi 

 CTeiieuH Ba-HtHO 6buo noflB.nenie paGoxLi ^poseHHa (1887), KOTopbiMT>iiocTaBJieHHbmBoiipocT> 

 iiaKOHeuii p'fcmem> ohWh biiojiu'I yAOB.ieTBopHTe.iBHO. <l>poBeHinj TmaTejtHO onpe^itjiMt 

 yiipyrocTH paajiH^iiibix'L ruApaTOBi, h, KpoMl; Toro, bx caMOMT> cnocoGi BbiHHCJieiiifl iiaiue.rb 

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BbiBOAT> KOTopoH MOHHO HaHTH B^ yqe6HRKaxT> *H.SHqecKOH xemIh. ^jih cnyqafl, HanpHiwfepT), 

 THApaTa CuSO^SHgO, paciiaAaiomarocfl ripn Harp-feBaHin na CuS0^4H20-hH20, Be.irHHHHa 

 K oCoaiiaqaexT) KOim,eHTpaii,iK) BO^flHoro napa, HaxoAflmarocfl Bt paBHOB-feciH ct> cojibio, q ecTb 

 KO.'iHHecTBO Tenjia, KOTopoe Bbi^'fejifleTCfl npn npHcoeAHHemn 18 KHJiorpaMM. BOAflHoro napa 

 KTb ooesBoaKeHHOH cojiH. OcTaeTCfl tojibko npeo5pa30BaTb upBBeAeHnoe ypaBeenie, iT05bi 

 nojyiHTb H3T) Hero nenocpeACTBeHHO onpe^'fejiHeMyH) bt, KajiopnineTp'fe BejiH4HHy, t. e. Ty 

 Ten.iOTy, KOTopaa BbiA'fe.nfleTCfl npH npHCoeAHHeniH bo^bi b'l jkhakomT), a He b-b napoo^pasHOMi. 

 cocTOflHin. BaM^THMi^, 1T0 npHBCAeHHoe Bbirae ypaBHenie npHMinaeTCH xaKme ki. HcnapeHiio h 

 Ha30BeMT> Mepesi) C„ — KOHn,eHTpauiK) BOAflHoro napa Bt npncyTCXBrn acHAKofi boabi, qepe.^-b 

 q„ — Tenjio, BbiAisJifliomeecH npn nepexoA'fe napa bi> TBepAoe rfcjio. Tor^a no npeAbiAyia,eMy 



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OTHomenie KOHneHTpanifi mojkho aaM-feHHTb OTHOuicnieMTb cooTBfccTBViomHXT) ynpyrocTen: 

 ynpyrocTH AHccou,ianiH cojih h ynpyrocTH nacbim,CHHaro napa npn Toil me TCMiiepaiyp'fe. 

 HasbiBaii 3T0 OTHomenie qepeai. F, mi'heM.'h 



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dT 272- 



SA'fecb Q ecTb xenjio, BbiAiuflH)iu,eecfl npn npHCoeAHHemH kt> oSesBOJKeHHon co.iih 18 KHJiorp, 

 BOAbi. Hto^bi BbmecTH vi3i> 3Toro AH*4>epeHu,iaJibHaro Bbipaacenifl SHaMenie aJ'a Q, HHTerpn- 

 pycMT) ero MCJKAy KaKHMH HiiCyAb rpaHHn,aMH Fj h Fj, npn MeMT> TeMnepaxypbi HM'fciox'b sna- 

 HCHie Tj H Tg ; TorAa HM'ieM'b 



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1) Frowein. Zeitsch. f. Physik. Chemie, t. 1, 8 (1887). 



