12 B. KypHJioBA. 



AnncHicML Sg Clg^). droTh yneiihin no oTnoiiiciiiK) kt. jiHccouiaiUR iie cr;iBH.n> nHKauoro pa3- 



.ilHMill MCHiAy HCnAKHMR H TBOpAblMH CHCTeMaMH. IJoaTOMV, 116 Ha6.IIK)Aa}f IIOCTOflHCTBa yupjTocTn 



npn BMA'fe.'ieHiR norjioii;eHHaro xiopa, oht> ciHTajii HsyqaeMhiH chctcmbi sa pacTsophi SgCl^ 

 B^ x.iop-fe. Meat^y T^wb MnxaaiHCi^) pair£e HaasiSepa, na ocHOBaum cbohxT) Ha6.!iK);T,eHiH 

 uocTPnoiiiiaro BhU'fe.iiPHifl iior.ioin,eHHaro x.iopa bt> saBHCHMocTii on-, xeMnepaTypw, c^iHTa.i'L, 

 4T0 x.iop-L Aaexi ct> S2CI2 A^a oiipeA'fc.neiiubixx XHMHHecKHXt coeAHHema SClg n SCl^. 



TaKoe pacxoJKAenie bo B3rji>iAaxT> BbisfciBajio HOBbin pHAt nscji'feAOBaHiH noAo5HbixT> 

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 SCI3 n SCI4, KaKT) onpeA^.ieHHbix'b XHM04ecKHXT> coeAHHenin, xo Mbi He bx iipas'fe npH.iiaraxb 

 KppixcpiH iiocxoflHCXBa yiipjTocxH Kb JKHAKHM'b CHCxeMaM'b. Ci) Apyron cxopoHbi, eciH npaBT) 

 Pl3aM6epT>, xo qtiui 06'hncnwrb cro.ib 3Ha4Hxe.iibHoe nonomenie xjopa coeAHHemeM'L SgCl2, 

 KaKT) He CHJIOK) xHMHqecKaro cpoACXBa. 



KpoMt HaamSepa, axoro ate Bonpoca qacxiio Kacaica Po3e6yMT>, ho h ero BbmoAbi, KaKTb 

 VBHAHM'b HHHte, Hacxo-UbKO HeonpeA'fe^ieHHbi, mxo npHXOAH.iiocb oxHecxncb ocoGchho BHHMaxejibHO 

 KT> HOCxaB-ieHHOH saAai-fe. OAHaKOiKi yjKi. Bxcpoii o6T>eKXT, Moero HaciiAOBaHia — hmphho 

 ciyqaii norjomeniH aMiwiaKa opoMHCXbiivrb aMMOHieMi), 3HaMHxe.ibHo ocBtxH-ii Aa.ibH'feHUjiH nyxb, 

 a xoA^ pasjioaceHia CHCxeMbi, coAepatameft Ha OAHy 'jacxHi^y xjiopncxaro i;HHKa AB'fe lacxnubi 

 aMMia^Haro ra3a, BuciH-fc Bbmcnnjii xapaKxepnyio ocoSeHHOcxb h'iHakhxt> cncxeMi n, BM-fecxi 

 ci> x^MT., AHCCon,iau,ia xaKoro poAa BemecxBi o5oco5HJiacb btj HOByio h Bno-HHi caMocxoaxejib- 

 nyK) o5.iacxb. 



Ms-iomeHie Bonpoca A0CCOi^iaH,m XHMHiecKHX'b coeAHHeHifi btj acnAKOMt cocxoaHm 

 cocxaBH.10 coAepatanie yexsepxoH h nocJitAHefl rjiasbi uacxoamaro coinneHia. 



TMBA BTOPAH. 

 YnpyrocTb AnccouiauiH co/ifiHbiX'b rMAparoB-b. 



Bonpoc'b o^Tj ynpyrocTH ARCcouiauin co-nanbixi. rnApaxoB'b Heo5xoAHMO AO-ivKen-b npeA- 

 uiecxBOBaxb Bonpocy AHCcoi^iau^H aMMia^Hbixt coeAHHeHiS. OoycjioBJiHBaexca aro, bo nepBbixt, 

 ncxopHHecKHMT> xoaomtj pasBHxifl npeAMexa, — rnApaxbi cojen 6buvL oahhmx> h3X> nepBbixT> o5t>- 

 eKX0BT> H3c.iif,A«BaniH ; Bxopaa Baainaa cxopoHa A'fe-na — 9to jiexoAbi onpeA'feienia ynpyrocxH 

 AHCCOuiauiH. Ha HaSjiiOAeHin pa3.ioacenia rnApaxoBX> uojiyHn.m, xanX) CKaaaxb, nciibixame pa3.raH- 

 Hhie iipH6opi)i, ocuoBaHHbie Macxo na HAeaxx> Bno.UH'fe oxjinMnbixij Apyn> oxx> Apyra, h HSCJi'tAOBa- 

 xejib, ycxpaHBaH)iu,iH HpnGopTb a-ia HayicHia ynpyrocxH AHCcoii,iau,iH KaKHXi> jmoyAB Apyrnx'b 

 coeAHHCHig, AOJiaceHx> pyKOBOAHXbca rkm.'b onhnowb, Koxopbm Hpio^p-fexenX) HScrtAOBaxeiaMH 

 Bt yKaaauHOH o6.iacxH. HaK0Heu,x>, bx. xpexbHXT>, HSJioatenie Bonpoca AHCcoii,iau,iH rHApaxoBt 



•) Isambert. C. R. 86, 664. (1878). | «) Michaelis, Lieb. Ann. 170,1 (1873). 



