PA3I0ffiEHIB XEMH'IECKHX'L COEJI,HHEHIJS, 0BPA30BAHHHX'B nOMOipHIESrB AMMIAKA COMMH. 23. 



CnpamnBaexcfl xenept, KaKHMT> oSpasoMi. onbiTHBra Maxepiajii), Kacawmiilcfl AHCC0ii;ia- 

 uIh rHApaxoBi., p-femaexi nocxaBJieHHiie Btimo Bonpocbi. 



PaacMaxpHBaii peayjibxaxbi HSC.n'feAOBaHiH ynpyrocxn AHCCOoiauin cojihulixt. rHApaxoBt, 

 Mti npeat^e Bcero HaxoAHMi), ixo com, aHaioraqHwa no cocxaBy, bx oakhxtb Cjiyiajix-B Aaioxi 

 OAHHaKOBbie no ^ncjiy h cocxaBy ruApaxti, Kb jipyrExi, cjyqaflXT> noAoSnofi saKOHHOCXH He 

 saMiiaexcfl. TaKT> nanp. CoClg h MCI2 j^aiox-L no ojHOMy rn^paxy cb 6-H)HacxHuaMH Kpncxaji- 

 jHsauioHHoft BOABi. MeanAj xfeMX, cxojil poj!;cxBeHHLia cojih, KaKT> BaCl2, SrClg h CaClg, pfeKO 

 BTb axoMt oxHomemn oxjiHiaioxca Apyri. oxt> apyra: bx xo speivw KaKT> BaClg Aaexx Ba 

 CI26H2O, BaClj 4H2O H BaClgHgO, cojih KajiLiufl h cxponnja ^aioxi xojibko no Asa rnApaxa: 

 CT> 6-K) H 2-Mfl lacxHitaMH boabi. Toace ao.ii3kho cKaaaxb nanp., cojiaxi) MgSO^ h ZnS04, 

 HST) KoxoptEXTb nepsafl oGpasyexi) ^Ba ruApaxa MgS047H20 n MgSO^eHjO, a Bxopaa xojibko 

 OAHHX THApaxi. ct 7-K) MacxHn;aMH boabi. 



Hxo6bI npHMHpHXb, eCJIH xo B03M0SKH0, yKaSaHHtlfl npOXEBOp-feqia, paSCMOXpHMl BHHMa- 

 XeJIBHO 1% IHCJIOBblfl AaHHBIfl, Ha OCHOBaniH KOXOpbIXT> npHXOAHJIOCb npHXXH K-b U0A06E0My 



saKjnoieHiK). 



Jl^jifl xjiopHCxaro 5apifl JEeKep-b^) jisterh cjrfeAywnpfl BejruHHHbi ynpyrocxeft bx> mhjijih- 

 MexpaxTj. 





BaClaGHgO 



BaCl22H20 



BaClgH^O 



5° 



5,4 



» 



» 



10° 



7,5 



» 



» 



30° 



» 



5,7 



» 



40° 



» 



10,5 



4 



60° 



» 



60 



20,5 



80° 



» 



208 



50,5 



100° 



» 



623 



271 



Jl^jifl xjiopHCxofi COJIH cxpoimifl JleKepx yKasbiBaex-b xo.ibKo ABa rn^paxa SrCl26H20 h 

 SrCl22H20 ^), a Mcmjij Tkwb AaHHbm ero ji^in ynpyrocxH npn nocxenenHOMi oxhhxIh boabi, 

 npH xennepaxyp-fc 100°, npeACxaBJiaioxcfl qncJiaMH 



SrCl2-Hl,90H2O 



230 MM. 





SrCl2-+-l,12H20 



230 » 





SrCl3-i-0,98H2O 



40 » 



(?) 



nocjitAHee ^hcjio oxM^qeHO aBxopoMB SHaKOMt Bonpoca h cxporo He ycxanoBJieHO, a MeacAy 



xtM-b 3X0X1) ptSKiit CKaiCKTb BX BCJlHMHH-fe yupyrOCXH BTj XO BpeM>I, KaKT> CHCXGMa nepexoAHXT) 



oxT> coAepataHifl 1,12 HjO kx> 0,98 H^O, cjiyacnxT) acHbiM-b yKasameMi na hobbih rnApaxi ci. 



1) Lescoeurs, Ann. Ch. Phys. [6], 19, 542. (1890). | 2) l. cit., p. 539. 



