PA3J0aEEHIE XHMBqECKnXT) ("OE,!I,nHEnitt, OBPA30BAHHHX^ nOMOHIEHlEMl ABMIAEA OO.IHMH. 31 



Ha TuMi> H.m niio.Mi. h31> oiineaiim>ix't ml-toaubl iic.itaa xaKHie h iiotomv, "no Ha6.iiO;i,aeTCH 

 .iHaHHTeJibuoe pacxoHtAeiiie MeatAJ nnciaMa pas.mMHbix'L naSjiioAaTejeH. 



Bt> caMOMTi A'fi-i'fe, TOHHOCTL oiipeA'FiJieHm Be.iHHHHLi ynpyrocTH ARCConiauin cooAuiienm, 

 oSpasoBaHiibixt nor.iom;eHieMT> a.MMiaKa co.nnMR, npeACTaB.ineTC/i eme MeHLraeir, t£mt> TaKOsafl 

 A.ifl yiipyrocTU AnccouiauiH co.ihhlixt, rnAparoBb. Bt 3tomt> ciy^aii ocoSeinio pasHxejuibifi 

 iipnM'fcp^ Aaex-L cpaBiieeie AaHHbixT> HaaMoepa h JKoamiu j^.in coeAniienui AgCyNHg. 

 PlaaMCepx') nciy^H-n. ji.m TeMnepaxypbi 100° cxfeAywinin BejiHTOin.i ynpyrocxn (5 Ha6.Tio- 

 Aeuin): 548, 548, 552, 549, 546 mm., a MejK^y xiMi /KoamiH^) Aaexx> jiJin xon Hie xcMne- 

 paxypbi 690 mhjijhm. (pacxoHtAeme noTrn bx 257o)- 



Maxepiajia ^a cpaBHeHin SA'fccb, BOo5iii,e, Maio, OAuaKo yatT. 3xoxt> oahht, npHM-fepi, a 

 xaKate n H-feKOxopbm Aannbm, npHBeACHiibiH unace, AOKasbiBaioxT, Majiyio xohhoctl oupeA'fejieHiH 

 xaKoro poAa. HaAO AJMaxt, ^^o ue oaho HecoBepmeucxBo Mexo^a ciyatHxi. npnqnHofi xaKHXi. 

 pacxoKAenifi, no n MHCxoxa pasiaraeMaro npoAyKxa, xoxa ^escnopuo MaBHOio iipaiHHOio aojijkho 

 c^ffraxb HeyAOB.iexBopnxcjibHoe ycxpoficxBO irpnoopoB'b, He Bnojni-fe rapaHXHpywmee cyxocxB 

 aMMia^Haro rasa. 



Hpn o6cyKAeHin pesyjibxaxoB-b, nciyqeHEbixT) npn HsyqemH AHCCOiuaii^H co.iaHbixi ra- 

 ApaxoB-b, Ha nepBbiH Mani) BbiABHHyxi) 6bLiT> Bonpoci) o 'qHC.i'fc h cocxaBi riTApaxoB'b y cojiefi 

 poAcxBCHHbix'b MeajAy coCoK) aieMeHxoBT.. J^amihm bx 3xomt> oxHomeniH, nojiyqeHHbia npn 

 Hsyqemu aMMia^nbixx> coeARHenin, npeACxaB.iHioxi) xy ate ABoficxBeHHOcxb: xaKi a-ih CaClg 

 HSBtcxHO Ca CI2 8NH3, Ca Clj 4NH3 h Bipoaxno Ca CI9 2NH3, a Ca Jj ya:e AaexT> Ca Jj 6NH3. 

 To^HO xaKHte a-ih Ag CI HSBtcxuo Ag CI SNHj, 2Ag CI 3NH3, a Ag Br KpoM-fe xoro Ag Br 2NH3 

 H X. A- Maxepiaji 3xotl 3A'£cb Kacaexca hoixh HCKJiK)HHxe.iibHO co.ieH, o6pa30BaHHbixi. oahhmI) 

 n xijMi) ate Mexa.ijroMT) h pasJiHHHbiMH rajiOHAaMH. B-b cjiyMaflXT> a;e rHApaxoBi) Mbi hm^jih 

 66.ibraeio qacxbio co.ih ct> pasJinMHsnin Mexa.waMn npH oAiioM-b h xomtj H;e ra-iOHAi. Taub KaKT> 

 anajornHecKaro <i>aKxn'iccKaro Maxepia.ia SA^cb ue HMterca, xo iipeatAe TfeMx riepeiixH Kh 

 co6cxBeHHbiMT> Hsc.i'feAOBaniflMT) BT> axoM-b EaapaB-ieHiH, ocxacxcn paacMOxpixb BKpaxii,-fe Bonpoci 

 saBHcnMOCxH ynpyrocxH AHCCoiuauiH h npoHHOCxn aMMiaiHbixi coeAHHemS on> cocxaBa 



CO.IIT. 



Bjiianie Ha ynpyrocxb AHCcou,ian,iH ra.iOHAHon lacxH cojin npH oahomT) Mexajurfe CKasbi- 

 Baexcfl ocoochho xopomo B-b ra.ioHAHbix'b co.iaxT) cepe6pa, ynpyrocxb Anccoii,iauiH Koxopbixi 

 nayicna 6.iaroAapn xpyAaM^ HaaM^opa h /KoanHH. HaaMoepX) (1S68) n3c.if.;i,0Ba.n> cocah- 

 uenia aMMiaKa ctj xjiopncxbiMX, ioAHCXbiM^ii uiaHHCXbiM-b cepeSpoM'b. ^.la x.iopncxaro cepeopa 

 HMT> dbiJiH o6HapyaceHbi coeAHHouia AByxT> xniiOBi>: AgClSNHg h 2AgC13NIIg. Jlin AgCl 

 3NHg Ha6jiK)AaeMbi 6bijm npn pasHbixij xeMnepaxypaxT> cxfeAyromia BeJiiRHHbi ynpyrocxH jiyic- 

 couiauiH (B'b Mii.i.iHM.): 



>) Isambert. L. c. p. 144. | «) Joannis, C. R. 118, 1161 (1894). 



