I'A.S.IOSEHFE XHMH^^ECKHX^ COE/i;HHEHlif. ORPAI^OBAIIHHXT. nor-TOniEHlRMI) AMMURA CO.THMH. '■V.\ 



3jifkchMbi eme pa3x ySkK^aeMCfl b^ Ma-ioii Toqiiocxn nscibAOBaHifiaToro po^a: b^ caMOMi 

 Atxfe, iipapameHie yiipyrocxH 2 AgC13NH.j iipn noBuiueHm TeMueparypw iia 1° (68° — 69°) 

 14MM.,Bh TO BpoMfl KaKT> iipH iiOBbnneiiin iia o^HUT, Mtc rpaAycL (xeMiiepaTypsi otl 69° — 70°) 

 66 MM. Orojib pfenifi cKaieKT> Bt HSM-fefieiiin BejiHiHHbi ynpyrocTH cl TeMnepaxypOH e^Ba jih 

 MOHtHO o6i>flCHHTb ecxecxBeHiibiMT) xoAOMT> iiBJieHifl, a He HecoBepraeHCTBOMT. oiipeA'fe.'ieHiH. 



Coe,nHueHifl ct aMMiaKOMTb io;iHCTaro cepe6pa, npoMt HsaMoepa, HScrfeAOBaj^ xaKwe 

 JfKoamiH (1894). H.saM6epT> ,'^aeT^ yiipyrocxH ARCCOitiaain xoJibKO ,pa coejiflHemsi 

 2AgJNH3 (B'b Mn.uHM.): 



20°0 



29 



60°5 



222 



34°0 



79 



70°0 



327 



53°0 



178 



76°0 



460 



45°0 



102 



63°0 



236 



5KoaHHH*), KpoM'fe 3Toro coeAHHeHifl, yKa.3HBaeTTb eme oaho Ag JNH,. Ynpyrocxn ;;hc- 

 con,iaiijiH axoro cooAHHeHin (pasHO h Ag J^.gNHg) aBxop'b nenocpeACXBCHHO bt> iHcmx-L He 

 npHBOAHTX, a AneTb jrauib aMnnpniecKyio <i)opMyjiy, CBflSbiBawmyio ynpyrocxR AHCCOAiauin Ch 

 xeMnepaxypoH paajioaceoiH, h yKasbiBaexx xeMnepaxypw AHCCOi],iau,iH hoatj HopMajibHbiMT> Aa- 

 BJieHieMi) 3°5 ajh Ag JNHg h 90° j^jia AgJVaNH,. 



CoeAHHeme aMMiana ct> SpoMHCxbiMi cepeSpoMi. Hayieno oauhmt> JKoaHHH, visjifkch ohx 

 jiaeTTb T0.1LK0 *opMy.'ibi, DpejicxaB.iniomia ynpyrocxn 4Hccon,iauiH B'b saBncHMOCxn oxt xcm- 

 nepaxypbi, npn qeMij xcMnepaxypbi AHCCOi^iaiiiH noji.'h HopMa.ibHbiMi. AaBJeHieMX) OKasbiBaioxcH 

 paBHbiMH Ag Br 3NH3 — 3°5, Ag Br% NH3 — 34° h Ag Br 2NH3 — 5 1°5. 



CoeAHHenie aMMiana ct uiaHHCXbiMi) cepeSpoMi HsyHeno JKoaHHH h HsaMfiepoM'b. 

 HaaMoepi) Aaexi) BejiHHHHy ynpyrocxn aja coeAHHeHifl AgCyNHgHpn 100°, KaKi) Bbnne 

 yKaaaHO, bt. cpeAHeMi 550, a-th xoro Hce coPAHHeHifl h xoh ate xeMnepaxypw JIKoauHH 

 jiaeTT> 690 mhji. 



Hstj npHBe^eHHbix'b Bbime npHM-fepoBij pa.3JioateHiH coeAHHeniH cojich cepeSpa Cb aMMia- 

 KOMX, Ch ocoSeHHOK) ptsKocxbK) npoflB.Tflexcfl BjiaHie raJiOHAHofi qacxH cojth. B'b caMOM'b A'fejrfe, 

 cpaBiiHM'b SA'fccb xeMoepaxypy AHCcoi;ian,iH noAt axMOC<i>epHbiMT> AaBjeHieM'b 



AgC13NH3 17° —21° (H3aM6e.pT>). 

 AgBr3NH3 3°5 (HtoaHHH). 



AgJNIig 3°5 



» 



AgCy;NH3 102° » 



Hs'b axHX'b conocxaBJieHiS BHAHM"b, qxo AgBr3NH3 o6jiaAaeTT> Sb.iLmeio pasjaraeMOCxbio, 

 TiM-L coeAHHenie AgG 3NH3, h, xoxh ioAHCxoe coeAHHenie Ag J 3NH3 He nayqeHo, OAHaKO, B'b 

 BHAy JierKOH pasjiaraeMOCxH AgJNH3, naAO npeAnojaraxb, tto oho pasjiaraexcn eme Jierqe, 



1) Joauuis, C. R. 118, 1150. 

 3aa. <ta8.-MaT. Ot«. 



