38 B. KypHJfOBA. 



6010 ajeRienTOB-L. O/inHaKOBocxi. MHCJia h cocTana rHApaTOBT> poscxBenHbixT) co^eft mli o6Hapy- 

 HCHJiH BT. npeAHAymcH r.TaB-fe AJia xixT, cjiyiaeBT), Kor^a MeTauraHecKyfo lacTt coin cocTaBJifljiH 

 poACTBeuHbie no xapaKxepy ajrenieHTLi, a rajiOHAi 6Mjn> oahhx h xoxt me. Hsi. npHBeACHHaro 

 BHAHMT), ^xo npn aMiMia^Hbixi coeAHHPHiaxi, noixn coBepmeuHO He HM-feexca n'oAo6Haro Maxepiajia. 

 TaKHMX> oSpasoM'L BonpocT> o6T) OAimaKOBOcxn iHCia h cocxasa coeAnHcnifi, oSpasoBaHHtixt no- 

 rjiomcHieMi) aiwMiaKa commh poACXBeHHtixi MexaJuiOBi), flB.3flexca oxKpbixbiM'L. Hxo6bi p-feiuEXb 

 ero, cji-feAyexT. nocxaBHXb cncxeMaxaqecKoe Hsyqeaie noAofetixi semecxBT,. Bx BH^y axoro a 

 BbiSpaji. A'la HSC.i'feji.oBaHifl ab'£ cojih aHaiornqnaro cocxasa, pyKOBojtflCB KpoM'fe yKasaHHaro 

 ein,e cj-feAyiomaMH cooopaateHiflMH : 1) 06'fe co.ih AOJiatiibi Aasaxt cl aMMiaKoivn. HicKOJibKo 

 coeAHHemfi pasjinqiiaro cocxaBa; 2) Be.nnqHHbi ynpyrocxefi ;nHccon,iauiii mofjih 6bi cijiKwrh wa 

 noBipKH rtx'i BLiBOAOB'b, KOH 6biJiH MHOio CA'fe.iaHbi oxiiocHxejibHo BJiiama Ha BejiHHHHy ynpy- 

 rocxH MexajunqecKOH lacxH cojih, h6o bt> 3xomt> oxHomeniH ;i,jifl aMMia^Hbixx coe^HHeHifl 

 HM'feexca Jiamb secbMa HesHaiHxejibHoe hhcjio AanHbix-b. HanSojiie uoAXo^amHM'b MaxepiajiOMT) 

 MHi KasaiRCb, noaxojviy, aMMia^Hbia coeAHHema Zn CI2 h CdClg, h6o oxHOCHxe.JibHO nepBoii cojh 

 wane HSB-fccxHO, mxo OHa ^aexi) coeAHHenia cb 6, 4 h 2 lacxHHaMH NH3, n naAO oHtH^axb no- 

 AoSHaroace oxnomeHia h a-m CdClg. CBepxi) xoro, aMMiaiHbia coeAHHema xiopncxaro KaAMia — 

 COJIH, MexajunqecKaa lacxb Koxopofi oSiaAaext BbicoKHM'b axoMHbiMT) B-fecoMi, aojiaKHbi o6.iiaAaxb 

 6ojibmeH Be-iHTHHOH ynpyrocxH h noxoMy aB.iaK)xca yAoSHbiMTb o6T>eKxoMi) AJia HadjuoAeaia. 

 HaKonen;!), BbiSopi) AJia HSCJi'feAOBaHia CHCxeMbi Zn Clg h NHg BaHceHi>, KaKi. yBHAHM-b HHHte, 

 eme Cb OAHOH cxopoubi. 



Co6cTBeHHbm HScntAOBaHin. 



MeTOAi) onpeAt/ieHifi ynpyrocTH AHCCOuiauiM reepAbixi CMCTeivii, oOpasoeaHHbix'b nor/io- 

 lUeHieMi) aiWMiaKa CO/iawM. npHSopi), KoxopbiM'b a HOJibsoBajicaAJiaonpeA'fe.ieHiaynpyrocxHAHc- 

 coi^aniH xBepAbix't aMniia^mbixt coeAHHemfi, cocxohxx. (pnc. 9) hsX) cji'feAywiii.HX'b lacxen: 

 1) mapHKOBOH xpy5KH c, Ky^a bhochxch BemecxBO, noABepraeaioe pasjiOHtemio, 2) pxyxaaro 

 ManoMexpa cx> sepKajibHofi innaJioH & h 3) pxyxHaro nacoca, npncoeAHHeHHaro kt> annapaxy 

 xpy6K0H a. MaHOMexpi) h pxyxHbifi nacocb, KaKT> bhaho Ha pMcyHKi, coeAHHenbi paAOMX. co- 



THyXblXT) BX> BHA'fe W CXeKJIHHHblXT, Xpy60KT>, KT, KOXOpblMT) Bl. I^eilXpaJbHOH TOCXH HpHHaHHa 



noATb npaMbiMTb yrjiOMT> cxeiv-iaHuaa xpy6Ka n, a k% axon nocji'feAnftH h npncoeAHHaexca aa 

 mjiH'&'fe mapHKOBaa xpy5Ka cb pa3.iaraeMbiMi. Bem,ecxBOMX.. Becb npndopTb — aa ii.'fejio naaa- 

 libra: H'lxx. HH MacxHKH, HH KayayKa. CHCxema cxeiuaHHbixi rnSKHx^b coiJieneHifi Aaexi bo3- 

 Moatiiocxb He onacaxbca 3a i^'fc.iocxb npH5opa bi. ciyaat BcerAa B03MoaiHbixi, xojraKOBT> h co- 

 xpaceniii. 06'heui) CHCxcMbi rndiKHX'b coyjieHiii ao aa'iajia A'feJieHiM MaHOMexpnaecKoii xpy6KH 

 ox-b Kpaaa, BCAymaro Kb mapHKOBcii xpySK'fe, okojio 100 Ky6. canxHM. OS-beivi^ mapHKOBOH 

 xpySKH AO Kpana o6biKHOBeHHO paBenxj 16 — 20 Ky6. canxHM. 



Ha6.iiK)AeHia cb xaKHMTb npHSopoMi. npoHSBOAaxca BecbMa npocxo. UlapHKOBaa xpy^Ka ct. 

 BemecxBOM'b, iipHroxoBieHHbiMX) AJfa pa3i0JKeHia, npncoeAHHaexca na uurH*-! ki> ii,eHxpajibHOH 

 aacxH iipHoopa. Ona oKpyataexca saxfeM-b BaHuoii, BiKoxopofi yAepaiHBaexca nocxoaHaaa xcm- 



