PA3JI0aEHIE XHMHqECKHXt COEAHHEHlS, OBPAaOBAHEHXT. IIOrJIOmEHIEMT) AMMIAKA COJIflMH. 41 



meiiifl xjopHCTaro i^nnKa aiviMiaKOMi, a noiyqHJi'L ero cjitAywmnMT) oSpaaoMT.. XjopncTbtH 

 UHHKT) pacTBopflJicfl Bi. 6e3BOAHOMT> cuHprfe H BT> pacTBopT> iipouycKajcfl aMMiaKTj, npaqeM^ 

 TOTqacTj ate BbinaAajix fifejibm ocaAOKT>, Koropbifi, Sy^yqa npoMbi-n. cnnproMX ii Bbicyuiemb 

 Bt nycTorl, corjiacHO anajiHay, coAepata.i'L 



IIojiyqeHO. Teopifl mh Zn CL 2 NHg 



CI 



41,64 



41,76 



Zn (no BbWHCi.) 



38,12 



38,24 



NH3 



20,05 



20,00 



99,81 100,00 



IIpoAyKTTb dTOTb iiOABepra-TCfl pasJiOHieHiK) bt, napaxi, aHH.iHua h Ha^xajrana. Bt> nepBOMi) 

 ciy^at BCJiHqHHa ynpyrociH pasHa 20 mm., a bo BTopoMT>, x. e. npn pasjiomeHiH bi> napaxT> 

 Ha<i>xajiHHa (216°), ona jiocxHrajia 45 mm. TaK-L KaKT> HaaMoepi wfl xeMnepaxypw 220° 

 AaexT) ynpyrocxL paBHyio 96 mm., xo HBiajicn Bonpocb, oSTiflCHaexca jrn cxojib p-fesKoe paa- 

 .iHiie B-L Be.iHHHirfe ynpyrocxH HCKjnoqnxe.ibno BJiiflnieMT. xeMnepaxypw, vuin ate pa3HHi;a 

 odasaHa pasjiirriH) npapoAbi ZnCl2 2 NH3, npnroxoBJieHHaro Heoj.HHaKOBbiMt cdocoSomx. 

 Bt> BHAy 3XHXT> AaHHbixTj fl ptiDH-icfl nocxaBHXB onbixH, H36paBT) 3a HCXoAHoe BemecxBO 

 aMMiaMHbifl coc;tHHeHiii, nojiyqeHHbifl Henocpe;icxBeHHO npHCoeAHHCHieMt aMMiaKa kt> xjiopa- 

 cxoMy ii,HHKy, CT) rfeMT), qxo5bi ycxanoBHXb, Meat^y ApyrnMH, n BejHiHny ynpyrocxH CHCxeMbi 

 Zn CI3 2 NHg npn HarpiBaniH bt> napaxi) Ha<PTa.iiHHa. 



JI,jiH no.iyieHia HSciiAyeMaro BemecxBa mhok) 6bMa Bsaxa npoAa>KHaa co.ib; xoth, -co- 

 rjiacHO aeaJiHsy, ona ne coii;ep;Ka.ia boabi, ho a^h 6b.ihmevi rapanxiii no.iyqema B03M0yKH0 

 HHCxaro npenapaxa a nocxynajii cjrfeA- o6pa30MT>. Btj ApeKcejieBofi cxKjranK'fe x.iopucxbm uHHK-b 

 Hacbin;a.ica xmaxcibHO BbicyuienHbiM'L aMsiiainbiMX rasoM-b. Ho-iyMeHHoe Bciu,ecxB0 pacxnpa- 

 .locb BT> cxynitt h saxiMX BbicymHBa.iocb btj BOSAyumofl (5aut npH 100° Cb x^mT), ixoobi 

 BM-fecrfe Cb BHii,'tjaEoni;iiMca aMMiaKOMi) yAajiHXb h noci^AHie c.i^ji,hi BJiaatHocxH, ecm ohh HM-fe- 

 .iHCb. SaxitM-L npenapaxTb nepeHOCHJica bx mapHKOByio xpyfiKy h 3ji,icb OKOH-qaxe.ibHo 

 Hacbiin,ajica aMMiaKOMij. Bt> BHAy snanHxeJibHaro yBOJinqeeia o6i.eMa npn norjiomenin 

 aMMiana, xaKOBoe npon3Bo,;n.iocb xo.ibKO ao coAep/Kania 5 — 6 'lacxnaX) na 1 qacxHoj^ x.io- 

 pncxaro unnna, h6o nnaqe Moatno ^bMO onacaxbca 3a OAHopoAuocxb cncxcMbi. Pacxnpaxb ate 

 E CHOBa nacbimaxb aMMiaKOMx. Ka3a.iocb onacHbiM-b, xaKT> KaKT> npenapaxx, mofl norjoxHXb 

 B.iaatHOCxb B03Ayxa. 



Be.!inqHHbi ynpyrocxH AHCCon,ianJH ajja oS.iacxn 6 — 4 qacxHi;bi n 4 — 2 qacxiTn,bi 

 aMMiaKa na 1 'mcTHuy x.iopncxaro UHHKa, bx. npcA'ft.TaxX) oninCKB Ha5.iK)AeHia, coBnaAa.iH ex. 

 qprc.iaMH H3aM6epa. TaKX., npn narptBanin bx, napax'b axMOBaro cunpxa, no.iv'ieHbi 

 cji^Ayiomia BejiHqHHbi ynpyrocxa btj mhjijihm. a-Jh pa3JiHiHbixx> coAepatanin nor-iomennaro 

 aMMiaKa. (Bo BctxX) Aajfbn-feiiniHXX) AaHHbixx> ooaX) kojir. NH3 pasyMiexca KOJinq. ero, ocxaio- 

 meeca nor.iou],eHHbiMi> cojibio no BbiA'fe.ieHiH aMMiaKa HJia Aocxnatcnia AanHoS ynpyrocxa). 



3ui. $H3.-MaT. Ot<(. 6 



