PA3;iOaiEmE XHMHiIECKHXI COEaHHEinfi. ()r>PA30BAHHHXT> nOMOmEHIElTB AMMIAKA COJDIMH. 43 



ripn oni.iTaxx iiafl-L pasjiOyKenieMi. b^ napaxi^ na-i'Ta-iniia Zn Clj 2 NHg, no.iyieHiiaro npn 

 jifkiicTBm aMMiainaro rasa na cimpTOBoii ])acTBopi> ZnClg, KaKt vjko Mr>i BnAt.in bwuio, bcjih- 

 HHiia yiipyrocTH AHf^coi^auin paBH>i.iacB 45 m.m.; wh iipeA't-iaxt ouihGkh na6.iioAeiiiH, OHa nB- 

 jflexcfl ToatAecTBCHHOH cb BejiH^HHOK) ynpyrocTH CHcxeMbi xoro ate cocxaBa, ho iiojiyieiiuoii 

 npH Henocpe;icrBeHHOMT> AiiHCXBin aMMiaMuaro rasa Ha cyxyw co.ii>. TaKHM^ oGpasoMi,, oth abe 

 Bern,PcxBa, iio.iyieHiibiH pa.jjraqHLiMH cnocoSaMH, He ox-inqaioxcn Apyn> o'n> Apyra no BejiH^nH-fe 

 ynpyrocxn AHCcoiiiaiun. 4xo6bi OKOHMaTcifcuo ySiAnrbcn bt> dxOiMT>, n nuifi pasx iioBxopHJit 

 onbixLi CT. BemecxBOMT), iiojiyqeHHBiMi) npn A'fencxBiH aMAiiaKa Ha ciiHpxoBoii pacxBopt Zn Clj . 

 npH 9X0MT) o^HapyateHO 6bijro nojiHoe cor.iacie ct> upeacHHMH onbixaMH. TaK'h, nanpHM-fepT,, 

 KorAa CHcreitfa coAepataJia na 0,6056 rp. ZnClg 0,1462 rp. NHg H.in — tfo xoate — 1,92 

 qacxHUbi, BejinmiHa ynpyrocxn paBHHJiacb 47,2 mm. 



ConocxaBJiflH AauHbm, cboh h HaaMCepa, naxoAHMi cxlAyiomifl BejinqHHbi ynpyrocxn, 

 oxstiaionjgifl cncxcMaMi) ct> pasjmqnbiMT. coAepHtanieMi aMMiaKa: 



20° 78° 216° 



ZnCl3 6NH3 103 mm. 1634,7 



(HaaMSepi) 

 ZnCl24NH8 57 mm. (31°) 402,2 mm. 



(H3aM6epT>) (h3T> 4 onpeA.) 

 ZnCla2NH3 — 43,6 



(hstj 8 onpeA.) 

 ZnCIa NHg — 6,7 



(nsT, 2 onpeA.) 



TaKHMi) oSpasoMT), xjiopncxbm n;nHKT> oSpasyexX) Cb aMMiaKOMX), KpoMt, xaKT> CKa.iaxb, 

 qexuoqacxnqobix'b coeAHHemn: ZnCl2 6NH8, ZnCl2 4NH3 n ZnCl2 2NH8, h coeAHHenie 

 ZnCljNHg. 



Bbi6opT> A-ifl H3Cjri&A0BaHifl x.iopncxaro n,HHKa oKasajiCfl BecbME npiiroAHbiMi. ji,jin nameii 

 utjiH, h6o, KaKT> Mbi BHAHMX), MOHiHo naS-iwAaxb qexbipe pasjinqHbixx coeAnneHia, o5pa3ye- 

 Mbm mn npn BaaHMOA'tHCXBin cb aMMiaKOMi). CnpauiHBacxcn xenepb, o^napyacnxcfl .m aHa.io- 

 rmnoe oxnomeirie k^ aMMiany y xjiopncxaro KaAMifl — cojin, 6jin3Ko cxoflm,eH kt> xjiopncxoMy 

 AHHKy no xapaKxepy MexajuiHiecKOH lacxn. 



nOMOmeHie aMMiaKa x/lopMCTWM-b KaAMieMl. Cojib, ynoxpeSjiaeMaii npn onbixaxi., Bbicy- 

 niHBajiacb ao nocxoHHHaro Bica h, corjiacHO aHa.TH3y, coAepatajia: 





IIojiyHeHo 



Teopia 



Cd 



61,05 



61,20 



CI 



38,65 



38,80 



99,70 100,00 



