48 B. KypHJiOBA. 





YnpyrocTt bt> cpeji,HeMX 





20° 78° 



CdCla 6 NH3 



330,95 (H3Tb 4 oiipeA.) (Soj-fee 1720,0) 



CdCla4NH3 



100,52 (h3t> 3 onp.) 1002,4 



CdClg 2 NH3 



24,63 (h3T> 3 onp.) 



CdCla NH3 



2,00 



216° 



336,10 (h3T> 6 onpeA.) 

 45,3 (h3i> 4 onpe^.) 



CpaBHHMi Tenepb nojyieHHbia Bejiaqmibi ynpyrocxH j^ia coeAHHeHifi xjiopncTaro Ka^MiH cl 

 aMMiaKOMT> CT. rfeMH ji,aHHbiMH, KOTopBia npHBe^eHM Bbirae ji.Jifi coeAvmemM aMMiaKa ct> xjio- 



pnCTBIMT) ItHHKOMTb. 



I^HHR-L KaAMiH 



npa 78°: 



MCI2 6 NH3 



1634,7 



(^0 



.i-fee 1720) 



MCI24NH3 



402,2 

 nnpn 216°: 





1002,4 



MCI2 2 NH3 



43,6 





336,10 



MCI2 NH3 



6,7 





45,30 



HsT. 3Toro conocTaBJieHifl MoatHO BbreecxH cjitjujiom^ia. 3aKiH)HeHifl : 



1) BjiH3Kifl no xapaKTepy CBoeMy cojh ZnClg h CdClg asmtl oAnnaKOBoe ihcjo aiwMiaq- 

 EbiK-h coejiHHeHiH CL on^wh H t£mT) ace cocTaBOiwL. 



2) YnpyrocTb AHCConianiH aMMia^Hbixi) coe,!i;HHeHiH, o5pa30BaHHbixT> xjiopncTbiMT, Ka^- 

 MieMT>, npa o^HHaKOBbixi) ycjiOBiflX'b : micia, lacxHUi) h TeMnepaxypbi — 6ojibme, n'i.wh ynpy- 

 rocTb coej),HHeHiH cb aMMiaKOMT. xjiopHCxaro n,HHKa n, xaKHMi) o6pa30M'b, npoqHocxb aMMiaq- 

 HbixT> coeji,HHeHiH ySbiBaext ex. yBe.raienieM'b axoMiaro B-Ica Mexai.ia. 



Hmso H cocxaBX. aMMiaqHbixT> coeAHHeniH xjiopHcxbixx> coien Ka^Mia h n,HHKa OKasajiHCb 

 OAHHaKOBbiMH. Bo BxopoH TJiaB'fe Hacxoaiii,aro coinHenia, mi, pa3CM0xp'§Hifl onbixnaro aiaxe- 

 piajia, Mbi yS'feAHJiHCb, hxo noAoSnaro me oxHomenifl aojijkho oacHAaxb jiia raApaxoBx. xiopn- 

 CTbix-b cojefi Kajibujifl, cxpoHn,ia h 6apifl. By^exx. ie HMfob Micxo axa saKOHHOcxb ajih rHApaxoBT> 

 H aMMiaTObixT) coeAHHemH Apyrnxx. aHaiorHqHbixx> coiefi — asjiflexca BonpocomX) oxKpbixbiMT>. 

 TojibKO CHCxeMaxaqecKia, a ne cjiyqafinbia H3CJi'£A0BaHifl, KaKx> xo 6biJio ao Hacxoam,aro Bpe- 

 MCHH, oKOHiaxciibHO ycxaH0BaxT> yKasaHHyio 3aK0HH0cxb. KaKX. 6hi hh 6biJio, HecoMHimio 

 OAHO, qxo A-Tfl xaKHXT) cojieH, KaKX> xjiopncxbiH KaAMifl n xiopncxbin hhhkX), aMMiaiHbia coeAH- 

 Heaia oSjiaAaioxx OAHHMb h xiiMX. ace cocxaBOMx>, n naAO oacHAaxb noAoSnaro aie oxHomema no 

 KpaHHPH Mipi :ji,Afi coeAHHeeiH cxojib ate 6jih3khxt. no XHiwaqecKOMy xapaKxepy. 



Hsjoateme onbixaaro Maxepiaja, Kacaiomaroca ynpyrocxH Aiiccon,ian,iH xsepAbixX) CHCxeMx>, 

 o6pa30BaHHbixx> uorjomeHieMX) aMMiana cojwmh, mhok) 3aK0HqeH0. DpeacAe I'feMX) nepefixH kx. 



