PASaOatEHIE XHMHqECKHXT) 0OEJI,aHEHl{{, 0BPA30BAHHIJX^ norJ10ni,EHIEMT, AMMIAKi GOJIflMlI. 5 1 



ecTfc oupejt'fejieHHoe xnMnqecKoe coeAHHenip, a hc pacTBopjb, PayjiL iipH6feraen> ki CJi%iyio- 

 meMV KpnTe])iM>. Ecjih, roBopnn, oivb, Aannaa ninxviocvb iipeACTaB.iflcr'i. oniJeAt-ieHiroe xhmw- 

 qecKoe coeAHHOHic, to stcL semecTBa iie iipeTepiiHTb HaMf.Heuia ao 'rlixT> nop-L, noKa xeMiie- 

 paxypa immc xoii, ji,Jin. Koxopoli ynpyrocTb AHCCOuiauin pasiia aTMoc-pepHOMy AaB.ieniio. Bt> 

 cjiyiai ace pacxBopa, npH BbiA'fejieHm norjiomeimaro rasa, B'fecT> BemecTBa ji,sn AanuoH xcMne- 

 paxypH AOJiJKeHT. y6f>iBaxb npaBiuitHO h iienpeptiBHO. H.Tb xa6.inu,bi, iiphboahmoh asxopoM'L, 

 BHAHO, nxo BtcL JKHAKOCXH, nMyHCHHOH, npu Hacbimemn cojh aMMiaKOMX iipn 0°, y6biBaen> 

 OMeub 6bicxpo ijpn xeMiiepaxypi oxt, 0° ao 12°. /^a.iie, hc CMOxpfl na xo, hxo xewnepaxypa 

 KOJie^jiexcfl B'b npeA'feJiaxx, oxx, 12° ao 18°, 3Ton> stcb ocxaexcfl nocxoflHHbiMi) h noxomy, 

 cooacuo Kpiixepiio aBxopa, ;KHAKOcxb xauoro cocxasa iipeACxaBJflexi onpeA't-ieHHoe xhmh- 

 qecKoe coeAHHewie. CocxaBi, ate ea KaKTb pasi oxB'£'iaexi> 'topMyji-fe Tpoocxa 



2NH,N03-h3NH3. 



B'b BHAy BbimeH3JioHteHHaro, npncxynaa k-b nscjiiAOBaHiio atHAKOCXH /^afisepca, iipeacAe 

 Bcero npeACxoflJio pimHXb Bonpoct, nui-feex-b jih SA'fccb nrfecxo nocxoflHCXBO ynpyrocxH ahcco- 

 itiaain HciaBHCHMO oxi cocxoHHia pasioatenia BemecxBa. HaKOHen,!,, Bt cjiyqa'fe yxBepAHxe.ib- 

 flaro oxBtxa AOJiaceH'b ^biJiT. flBnxbc/i hobmh Boiipocb: Aaexi) .to npaeo 3xo nocxoaecxBO ynpy- 

 rocTH CA'fejaxb saoioHeHie o CHCxeM-t, Kau'b oiipeA'fcjeHHOM'L XHMHiecKOMX. coeAHHeHin. 



MeiOAT* M3C/itA08aHifl. B'b BHAy ocoSeHHocxH pa3.i03KeHifl jkhakoh CHCxeMbi, MexoAXj, 

 KoxopbiM'b fl xenepb nojbSOBajicfl, oxjiHiajicfl orb MexoAa, oriHcanHaro mhow Bbnne. flpHoop'L 

 cocxoaj-b (pHC. 10) hstj mapHKOBon xpy5KH (&), bi Koxopyw noM'tin.a.iocb HCiibixyeMoe Beme- 

 cxBO. ITpn noMom,H xpexi) oxB'fcxBJieHin (d,d,d,) axa xpySo^a coeAHna^iacb 1) ch ManoMexpoMt 

 (/") Cb sepKajibHOH niKajiOH, 2) cb pxyxHbiM'b raaoMexpoMb (a), cnaSateHHbiMT, acnnpaxopoN^ (c) h 

 3) c-b pxyxHbiurb uacocoMX FeHciepa, coeAHHeHHbiM-b lepesi) xpy6Ky (e). OxAijibUbia qacxH 

 upnSopa coeAHHflJiHCb Apyrt ch ApyroMT> Ses-b cypryqa hjih MacxHKH, cujiomb na oahoh iiaiiK'fe, 

 iipn noMomn thSkhxti coiJieuenin (ddd), CAhjianHbixTj H3'b cxeK.ianHbixT> xpy6oKT>, cornyxbixx. 

 B'b BHA'fe w (AJiHHa KOJi'fcHa 0K0.10 V^ apiu.). ITpn xanoM-b ycxpoficxBi aniiapaxa bo3Mo>kho 6buo 

 He SoflXbCfl c.iyiaHUbix'b coxpacenifi, a, r.iaBnoe, MoacHo Gbi.io B36axrbiBaTb aiHAKocxb B'b 

 mapHKOBOH rpySK'fc, hxo npn onbixax'b asjiajocb BecbMa cym.ecxBeaHbiM'b. Be3'b BCxpaxuBaHia 

 acHAKOcxH norjomeHie a.MMiaKa, KaK-b iipoHCxoAamee cii iiOBepxHocxH, HAeTb qpe3BbmaHH0 

 MeAJiCHHO. ^aaie caMoe Aocxnaieme HeHSM'feiinoH ynpyrocxn a-w AaHHaro cocxoflHia cncxeMbi 

 iipH BbiA'LieHiH aMMiaKa xpeSyex-b no xofi ate iipn'ma-fc aobo-ibiio iipoACia^Hxejibuaro speMeHH. 



Onbixbi HaiiTnajiHCb cb xoro, hto B'b luapnKOByK) xpy^Ky nepes'b Bepxnee oxBepcric 

 BBOAHJiacb xopouio BbicymeuHaa aeoxHoaMiuiaHHafl co.iib, h BCJciA'B 3a rfeji'b axo oxBepcxie 

 sanaHBajiocb. TpyGoqua, cnapajKeHHaa xaKDM-b oCpasoM'b, iipHnaHBa;iacb ht, u'fenH rnCKHx-b 

 coHjeeeHiH, h oxKpbiBajicfl Aocxyn'b Kb ra^OMexpy Cb awMiaKOMb. 



HanojiHeuie raaoMexpa npoHSBOAMOCb upc'ABapHxe.ibHO H3'b (jco6aro pesepByapa, Koxo- 

 pbiM'b cjyatHJia JiHiwoHaAHaa oyxbiJiKa cb SHaraxejibHbiMXj Ko.ni'iecxBOM'b atHAKocxH ^1,anBepca. 

 KaK-b HSB'fecTHO, oSbiKHOBeHHbiH cnoco6^ cymeniH nponycKaiiieM-b rasa 'lepeai, unjiiiiiApbi 



