PA3J0ffiEHIE XHMHqECKHXT. COEj;HHEBlfi, OBPASOBAHHHXT. nor.TOmEHIEM'b AMMIAKA CO.IHMH. 59 



c) 0,8308 rp. co.ih iior.iou;eHo 0,3700 rp. NHg, t. o. iia 100 B-fec. toct. NH^NOg— 44 

 NHg. OcaAOKT> Hc Bwna^aeTT. n npn — 30°. 



TaKHMT) o6pa30MT>, <paK'n> H3M'I'.iienifl pacTBopHMOCXH a30TiioaMMia»moH co.ih bi> aMsriaK'ft 

 ;ioji>KeuT) craxaTbCfl Brio-iiit ycTaiioB.iieHHi,iM']>. A axoTi. <i>aKTT. yme OKOHHaTe.M>HO ncKJiionaeT'h 

 npcAHOJioJKenie, qxo H3y'iaeMaa CHCxeMa iipoicTaBJweit onpeA'h.ioHHoe xHMH'iocKoe coeAHHenic. 



SaKaHiHBaa 3TnM'b Hsyyeiiie jkhakocth ^aiiBepca, mbi MOHteMt ;;ooi>iTbie pesy.ibTaThi 

 pesioMHpoBaxt cjitAyiomniviH c.iOBaMH: 



1) JKhakocxb /l^aHBepca, o^pa^iyiomaflCH upn norjioiueHin aMMiaita aaoxHoaMMia^inoio 

 coJibH), npno.iHH;aexcfl no xapaKxepy paa-ioatenifl Kb pacxBopy NII^NOg bt> aMMiaufc, npmeMT> 

 pacxBopHMOcxb cojiH pacxexT> ch noBbimeiiieMi) xeiMiiepaxypbi. 



2) Ynpyi-ocxb anijiiaKa, AasaeMaa TpoocxoMi) jiJin cooj^Huenifl 



2NH,N03-»-3NH3, 



oxB'fenaexi. xoMy cocxoHniio cncxeMbi, npn KOxopoMt oea npe;icxaBJiflexT. atHAKOcxb h xBepAoe 

 xi.10, H, noTOMy, 



3) KojiHiecxBO nor.iomeHnaro aMMiana, oxshqaEomec, no Tpoocxy, cocxaBy yKasanHaro 

 cocAFHeHia, cooxBtxcxByexT. cocxaBv nacbimennaro pacxBopa npn 0°. 



Bt> Hanajf. axon rjiasbi a yKa3biBa.n>, "ixo BoceMb .t£xt. HaaaA^ Po3e6yMi»\) 3a,itaBa.ica 

 BonpocoMT>, S-iHSKHMT) Kh npe^Mexy nacxoamaro nac.if.AOBaHia. BbiBOAbi. Koxopbio ow-b A'fe.iapx'h 

 conocxaB.iaa coScxBCHUbia nacxfeAoBft'iia n pcsy.ibxaxbi. no.iyqeHUbio ApyrnMir aBxopaMH, 



J1,0C.10BH0 C.Tfe/t}'K)Ul,i(.' : 



1) IIocxoaHCXBO ynpyrocxH bt> j;HCCon,iHpyK)iu,iix'b a;HAKOcxax'b HaGjiw^aexca xo^JbKo bt. 

 ciyiat, Kor^a pasjiaraexca HeoAHopoAHaii CHCxema. 



2) 3xa nocxoanHaa ynpyrocxb He Moatext ciya^nxb AOKaaaxejibCXBOMi., qxo HiHAKOCXb 

 t'CTb onpejitjiennoe xn.MHiecKoe cot'AHHeme. 



3) ITocxoaHCTBO ynpyrocxn ne ^naexi. cpcACXBa piuiHXb, AO.iatao jh pascmaxpHBaxb axy 

 jKH^Kocxb KaKT. CM^Cb onpeA'fe-TeHHbix'b xnMn»iecKHXT> coeAHHeniif. 



4) HsM'feneHie ynpyrocxH it.ia BcfcxT. OAHopoAUbix'b atHAKocxcn jiiWTb apry.MenxT, B'b 

 iio.ib3y paRHOM'fepHaro pacripci.'fe-ipnia lacxnui. rasa, saK.iio^enHaro B'b sxnx-b >KHAKocxax'b. 



OxcK);ia Mbi BHAHMT,, Hxo posvjibxaxbi, nojy'ieinibio miiok), no cxoar-b bx> npoTHBopt'iin 

 c'b BbiBOAa.MH Po3e6yMa; Bonpocx. BCe aio ocxaexca iicBbiacnpHHbiMi, ii HMenno cb caMoii 

 cymccxBCHHon cxopoiibi: aoji'.kho .ih oxpnuaxb, Kb le.My, noRiTAnMoMy, CKJionacrca Poae- 

 6yMi., xHMH'tecKyK) HHAHBHAyajbHOCxb KHAKHXT) cncxeMT>? 



•) Koosebooni. Recueil dea trav. Chim. Pays-Bas, 4,378. (1885). 



