60 B. KypHjioBA. 



BAVMbiBancL bl MHCia. Aiiniibia Po3c6yMOM'b a-ih ynpyrocxn cucxcMbi, oopasyiomencH 

 iipn iior.ioiuciiiH aiviMiaKa GpoMncxbiMT) aMMOnieMi., n npHiuejit kT) aaKJUo^iciiiio, mto axa CHcreMa 

 MOHjeiT) oKasaTbCfl Becbuia npHro^HOH ji^in BbmcHemfl axoro Boiipoca. TaK-b KaKX> ji;aHHbixT) 

 Po3e6yMa, KaKi) yBHAHMT> hhjkc, oKasa^iocL HCAOCxaxoqHO, xo noaxoMy, iiocii HSCi'tAOBaiiiH 

 jKHAKocxn ^I,aHBepca, n npnc n iiM'b in, Hsyieiiiio cncxeMbi, o6pa3yK)iii,eHCfl npH nor-iomeiiia 

 iiMMiaKa 6])0.Mncrbni'b aMMonieMb. 



flOMOlueHie aMMiaKa 6pOMMCTblWb aMMOHieMt. Cnyian nor.iomeHia aMMiaKa Sponm- 

 cxbiM% aMMOiiioMb paiii.e jipyraxx, 6hUT, ii3CJif.,i,0BaH'L TpoocxoMT>. 9xoxi> aBxopx^), iipHnpo- 

 nycKaiiin NHg bt> HBr h oxja^aeniH iipn pasHbix'b xeMiiepaxypaxij Bo^rouoBX, o^pasyioma- 

 rocii iipoAyKxa, nciyTOJi cTfe^yromia BemecxBa: 



l)HBr2NH3 bromliydrato biammouiacal, 



2) HBr 4NH3 tetraammoniacal, 



3) HBr 7NH3 heptaammoniacal. 



JlnH axnxT) Beui,('CXBx, aBxopoMX> ,i,aHbi ynpyrocxn bt, saBHCHMOcxH oxt, xeMnepaxypbi 

 6(!3'L yKasaiiiH. KaKi h btj cnyiat h^hakocxh /l^aHBepca, na iipcA'fc.ibi, bt> Koxopbix^ im^JHO- 

 jislgtch nocxoHHCXBo ynpyrocxn'pasjiaraiomarocfl BemecxBa. KpoMt xoro, i[jih Bxoporo h3x 

 npHBe^eHHbixTj Beui,ecxBT> hmi yKa3aHa xennepaxypa n.TaB.ieHia -t- 6° n 3aMep3aHia — 20°, a 

 AM nocjitAHaro BemecxBa xeMncpaxypa njiaBienifl — 20° h saMepsaniH — 45°. Po3e6yMT>^) 

 jiajitc noBxopH.iX) onpeA'f'-ieHie xennepax^'pbi luaBjeniji HBr 4NH3 h name.ii) ee paBiiofi -1-8, 7° 

 H, Kpojii xoro, Aa.i'b ynpyrocxn AHCCou,iaii,iH cncxeMbi ci> coAep»;anieM'b oxt> 3,04 — 2,04 qacxnuxi 

 aMMiaKa na 1 lacxHuy NH^ Br. Hpn axoM^b aBxopoMTb KOiicxaxnpoBaiio nocxoHHCXBO ynpyrocxn 

 AHCcon,iaii,iH bt, npcA'ft.iax'b yKasaHHbixi) coAepaKaiiiii h, ixo 6oAe Bcero niixepeceo, jiih oa- 

 iioro H xoro ace cocxaBa CHCxcMbi nwb iiojiyienbi pa3.iniMHbm ynpyrocxn bt> 3aBHCHMocxH oxx. 

 efl arrperaxnaro cocxoHHia. 



BoxTb no^CMy noAo6ubm ciy^aH Ka3a.TCfl mh'£ noAxoAflui.HM'b a-ih Moefi ix^m. Ho j[.m xoro, 

 Hxo()bi npeACxaBiixb no.iHyio Kapinny pa3.!ioJKeHifl, Heo6xoAHMbi «i>aKXHMeci;ia ji^mrnhm ajih chc- 

 XGMbi ox-b coAepaianifl b-b 2 qacxHn,bi ao nojniaro yAajtenifl aMMiana. Hncjia am 3XHX'b npeA'fe- 

 .lOBT, cocxaBa ne Aanbi Po3e6yMOMT>, a MeatAy xi;Mi> ohh flBJi/noxcn BecbMa cyin,ecxBeHHbiMii. 

 HoKa BbiAf;.wjexcfl iH^pBag 'facxni;a hst, coeAHHenia NH4Br3NH3, ynpyrocxb aMMiaKa, Aonyc- 

 xnMT>, ocxaexcfl nocxoaimoH, ho ocxanexca .m oiia xaKoii ao nojiiiaro BbiA't-ienifl ra3a — flBJiaexca 

 BonpocoMT. oxKpbrrbiMTj. HuAHBHAya-ibiiocxb XHMHMecKaro coeAHHCHia, no cyin,ecxBy aB.ienia, 

 xapaKxepH3yexca hmchuo pa^jio^KenieMX), xaK-b CKasaxb, noc^AUHXi cjiiAOBi. BemecxBa. CaM-b 

 Po3e6yMX, npHHHMaa NH4Br3NH3 3a onpeA'fcJieuHoe xhmhtcckoc coeAHnenie, rjiaBHbiMX 

 o6pa30Mi,, onnpaexca npn ^xoM^ ne na Aannbia AHCCOu,ian,iH, KaKx> 6hi c.TfcAOBa.io oacHAaxb, a 



1) Troost, C. R. 92, 705. | 2) Kooseboom. Loco cit. 361. 



