PA3JI0aEHIE XHMHilECKHXl COEJI,IIHEHlfi, 0BPA30BAHHHX^ nor.TOIHEniEMT) AMMIAKA CO.IJIMH. ()7 



Btime ;;jifl CHCxeMbi, oopa.JuBaiinoii iior.ioiuoiueMi. aMMiaua opoMiicTMM'i. aMMomcMb 

 MLi BHA'feJUf, 'iTO onpeA'fe-ieHHoe XHMnqecKoe coeAHiienie NH^BrSNHg, ()y;i,yMH pacnjiaB^iieiio, 

 aaeiTj naAaroinyio KpnByio ynpyrocTH ao Toro iwoMeuTa, nona h.tb pacTBopa ne BbinaAeri. 

 TBepAoe Tkio. TaKHMi. oSpasoMi), Heo6xoAHMO AonycTHTh, ixo naAaiomia npHMbm, pircyiomiH 

 KapxHHy pasJOHceHifl acHAKOCXH, o6.iaAaK)XT> H'feKoxopwMH ocoSennocxflMH bt> xomt. cjiyiai;. 

 Kor^a pas.iaraiomaflCfl HCHAKaa cncxeMa oSpaaoBana rasoMt, xHMH>jecKH A'£iicxByioiii,nM'i, iia 

 XBepAoe T'fcjo. Ecjin 3xo xaKi., to xenepb flB.iaexca Boiipocxj, kukhmt, oGpasoM-L hi, m^iUieiim 

 BejiHHHOT> ynpyrocxH b^ saBHCHMOCTH oxt> oxHOCHxe-itHaro coAepa^anifl rasa CKaatexcfl nepe- 

 xoAT> MeatAy AByMH cncxeMaMH, bt. xBepAOMt cocxoflHia npejncxaB.i/iK)ii]iHMH ^sa onpeA'fe-ieHHbm 

 XHMHiecKifl coeAHHeHia. Hxo5i.i pfcinnxb axox-b BonpocT>, fl npeAnpRHfl.'n> nsyienie pasjoajenin 

 CHCxeMbi ZnClj 2NH3 bt. acHAKOivn, cocxOiiHin. TaKT> KaKx Bbirae mhok) 6huo ;i,OKa3ano na ocho- 

 BaHiH H3yqeHifl ynpyrocxn AHCcoii^iai;m xBepAon cacxeMbi, mxo ZnClg Aaexi cb awMia- 

 KOMi, MeatAj' npoHHM-b, coeAHflema ZnClj 2NH3 h ZnClg NHg, xo xoAt pasjioateHia cncxeMLi 

 Z11CI22NH3 BT> ajDAKOMTb cocxoaaiH Mon, ^axb otb^xtj na nocxaBJieHHLiS Bbiuie 

 BonpocT). 



Pas/iomeHie wmakom CHcreMbi, coAepwaiueii ABt nacTHUbi aMMiaKa Ha 1 nacTHuy ZnCl^. 

 CncxeMa, coAepatamaa ab^ ^acxnubi aMMiana iia 1 Macxniiy xjopHCxaro uniiKa n cjiyHtHBinan 

 AJifl MOHXT) Hsci-feAOBauin, npHroxoBJia.iacb abohko : hjih ripn A'fencxBiH aMMiaKa na cnnpxoBOH 

 pacTBopi) xjiopacxaro AnHKa, hjih >Ke HenocpeAcxBeiiHO nst cyxofi cojih h aMMiaHHaro raaa. 

 3xa CHCxeMa yate npn HarpiBaniH b-b napaxx aMHJioBaro 3*Hpa SeHSonnoH khcjoxh (267°) 

 cxanoBHxca OAHopoAHOio atHAKOCXbio. 



HsciiAOBaHie pasjioseHia axon hchakocth 6bUo npoHSBeAeno mhok) ci> Thwh npH6opoMT>, 

 KoxopbiMT> fl noJib30BajiCfl npn HayqeniH ynpyrocxn AHCCoii,iauiH xBepAbixi> cHCxeMi.. IIpaBAa, 

 ^xo ODLixLi Cb 9XHMT. npH6opoMT> A-TH c.Tyqafl pasJOHicHifl mHAKOCxen xpedoBajin SHainxfiJbHO 

 6ojn>me BpeMeun, h^m-b ct> npHoopoM'i Apyroro Bbipa6oxanHaro mhow xnna, OAnaKo, HJin 

 ciyqafl hhakoh CHCxeMBi, oSpasoBannon xjiopncxbiMi uhukomt. cl aMMiaKOMi,, nMbsoBaxbCfl 

 HMeHHO 3XHMT> npn5opoMi. MHi Kaaajiocb 6ojrfee BbiroAHban>. 3A'fecb mapHKOBafl xpySna cb paa- 

 JiaraiomHMCfl BemecxBOMT> npncoeAHiiajiacb kt. npnSopy iia mjH*^, xaKt qxo Moacao 6huo 

 coAepatanie aMwiaKa b-b pa3J(araK)in,eHCfl CHCxeMi oiipeA^jaxb iienocpeACXBeimbiM'b BSB'l^mHBa- 

 HieMi>, lepesi. ^xo ysejiHTOBaexca caMaa xoihocxb onpeA'^JieaiH. T&Kb K&ixb ynpyrocxb BbiAi- 

 jiaiomaroca aMMiana bt> axoM-b cjiyqai 3aBHCHXT> cym,ecxBeHHO oxt> cocxoHHia pasjioateHia bc- 

 mecxBa, H 3aAaqy HacTfeAOBaaia HMeaao cocxaBJiflexTj cxporoe BbiacHenie saBHCHMocxn MeaiAy 

 ynpyrocxbK) AHCCoi;iai;iH h KOJimecxBOMT) norjioin,eHHaro rasa, xo a n BocnojibsoBajca npnSo- 

 poMT> axoro xnna. 



KorAa paajiOHteaie BemecxBa, nojiyqeHHaro npn AiiicxBin aMMiaKa na conpxoBofi pacxBopi, 

 xjopacxaro itniiKa, npoHCXOAHJio btb napax-b aMHjroBaro a^^npa 6PH3oiiHon khc.ioti,!. iio.i\'ioni,i 

 SbiJiH cji'feAyiomifl BejiHqHHbi ynpyrocxn: 



