50 SUBSTANCES SOLUBLE IN ALCOHOL. 



might be made in omitting this treatment, since on rendering 

 alkaline and shaking with petroleum spirit this solvent would 

 take up a little chloroform and would consequently be no longer 

 pure. After, therefore, tlw remainder of the chloroform has been 

 removed by petroleum spirit, the liquid may be made alkaline 

 with ammonia,- and the agitation with the same solvents repeated 

 in the same order. In addition to these three liquids I have, 

 however, after agitation with chloroform, employed amylic alcohol 

 for detecting certain poisons. It removes morphme, solaiiwae, 

 (§ 171), saMcine {§ 167), and some other substanties from their 

 aqueous solutions with special facility. 



It is principally alkaloids that are removed by petroleum spirit, 

 etc., from ammoniacal solution. Petroleum spirit dissolves, for 

 instance, traces of strychnine, brupine, emetine, . veratine, sdbadiUine, 

 and sabatrine. All these substances are, however, more easily and 

 completely taken up by benzene and chloroform. 



But petroleum, spirit is specially valuable in the examination 

 for the so-called volatile and, at ordinary temperatures, liquid 

 alkaloids, such as coniine, meihylconiiiie (and conhydrine), ■ nico- 

 tine, lobeliinei sparteine, alkaloids in piTnento, capsicum and 

 Sarracmia purpurea. Anilirie, trimMhylamine, and allied sub- 

 stances are also dissolved by it (§§ 1^1, 239). In examining for 

 volatile alkaloids I have advised agitation of the aqueous liquid 

 with petroleum spin tj and evaporation of the solvent, after separ 

 ration, at a temperature of about 20°, on glass dishes previously 

 moistened with strong hydrochloric acid, on which the. hydro- 

 chlorides of ihe alkaloids will partly, at all events, remain 

 behind. A freshly-prepared dilute solutaon of hydrochloric acid 

 gas in ether may be advantageously substituted for the usual 

 aqueous acid. 



Benzene removes from ammoniacal solution, in addition to the 

 alkaloids already mentioned, atropine, hyoscyamim, physostigmme, 

 pilocarpine, gelsemim, taxine, quinidine, narcotvrie, codeine, Ihebaine, 

 delfhinine and delpihinoidine, aconitine, aspidospermirte, perarine, and 

 a trace of cinchonine. (Cf. § 171.) 



In addition to these, again, chloroform dissolves from ammoniacal 

 solution cinchonine,- papaverine, narceine, nupharine, the alkaloids of 

 celandine, and small quantities of morphine (§171). 



§ 57, Direct Tests for Glucosides, Alkaloids, etc. — The number of 

 acids, glucosides and alkaloids (cf. § 21) that may be isolated by 



