118 ETHEREAL OILS- 



evaporation is less than 0-001. 10 cc. would, therefore, contain 

 0'163 gram instead of 0'166 gram. 



§ 137. Estimation vfith BisulpUde o/ Car Jore.— Instead of petro- 

 leum spirit, Osse also tridd bisulphide of carbon, as recommended 

 by Hager * for the quantitative Estimation of camphor, as well as 

 mixtures of both liquids, without attaining better results. He 

 has therefore decided in favour of petroleum spirit alone, which, 

 however, should not contain any oils boiling at a temperature 

 higher than 40° C. 



In analyzing- vegetable substances such a petroleum spirit is 

 preferable to mixtures of the' same with bisulphide of carbon, as 

 it has a lesser solvent power for resins, etc. -Ethereal oils may 

 be extracted from th«ir aq^aeous solutions by petroleum spirit,^ 

 and may therefore be estimated in the aqueous portion of the 

 distillate (§ 24) by ^baking. with ithat solvent and evaporating a 

 measured quantity of the solution after separation from the 

 aqueous liquid. I have also employed this method for estimatiiig 

 the essential, oil in the official aromatic waters. 



§ 138. I'nfiuence of Fixed Oil. — Osse also made experiments with 

 the view of ascertaining whether the presence of fixed oil could 

 aifect the determination of ethereal oil,, either by itself increasing 

 in weight during the exposure to the air or by preventing the eva- 

 poration of the ethereal oil at, 110° C. He found that a pretty 

 close approximation to the truth might generally be arrived at by 

 deducting 6 '09 to O'l per cent, from the weight of tie 'fat after 

 heating to 110°. No appreciable error would be caus:ed by the 

 oxidation of the' fixed oil during the evaporation of the petroleum 

 spirit, as the presence of the latter, even in small quantities, pre- 

 vents or delays such change. 



0;875 gram olive oil w,as mixed with 0-051 gram oil of turpen- 

 tine and heated for an hour to 110° 0. The weight of the 

 residue was. 0-875 gram, which did not alter if the heating were 

 continued two hours longer. 



1-4265 gram olive oil'ahd 00575 gram oil of cinnamon weighed 

 after 



1 hour at 110°. . . 1-436 gram. 



2 „ • „ . . . 1-4335 , „ 



3 ,, ,, . . . . 1-4315 „ 



' I^harm. Centralblatt, xiii. 449. 



' Dragendorff, paper read .it a meeting of the German ' Apoihekerverein ' 

 iu Cologne, 1873 ; ' ErmitteluHg der Gifte,' Snd ed.,.46, 1876. 



