Prof. T. Carnellev on the Periodic La 



w. 



499 



Table I. — Experimental Data. 



Chlorides : — 

 Methyl chloride 

 Ethyl 

 Propyl 



Butyl 



Arnyl 



» 

 Heiyl 



Heptyl 



Octyl 



Methylene dichloride 

 Ethylene „ 



Ethyhdene 

 Propylene ,, 



Butylene 



Amylene 



Hexylene 

 >> 

 >> 



Heptylene 

 Octylene 



Constitution. 



CH3.CI 



CH 3 .CH 2 .01 



CH 3 . 0H o . CH 2 . CI ... 

 CH3.CKCl.CH3 



ch 3 . (ch 2 ) 3 . cr 



CHMe 2 .CH 2 .Cl 



CMe 3 .Cl 



CH 3 .(CH 2 ) 4 .C1 



CHEt 2 .Cl 



CHMePra.Cl 



CHMe 2 . CH 2 . CH 2 . 01.. 



CHMePr£.Cl 



CMe Et.Cl 



CH 3 :(CH 2 ) 5 .C1 



Me.(CH ) 3 .CHCl.Me.. 

 CHMe 2 . CMe 2 . CI 



ch 3 ':(ch 2 ) 6 '. ci ...:::::: 



CHMe 2 .(CH 2 ) 4 .Cl(?).. 



CMe 3 .CMe 2 .Cl 



Pr/3 . (CH 2 ).;. CHMe . CI 



CH, . (CH 2 ) 7 . CI 



C 6 H 13 . CHMe . CI 



C 5 H n . CHEt . CI , 



8 H 17 C1 



CEt 2 Pr«.Cl 



8 H 17 C1 



CH 2 C1 2 



CH 2 C1.CH 2 C1 



CH 3 . CHC1 2 



C1.(CH 9 ),.C1 



CH 3 . CHC1 . CH 2 C1 ... 



CH 3 . CH 2 . CHC1 9 



CH 3 .CC1 2 .CH 3 ." 



C 4 H 8 C1 2 



CHMe 2 .CHClJ' '..'.' '.'.'.'. 

 CH 3 .CC1 2 .CH 2 .CH 3 ... 



6 H lfl Cl 2 



Pr«.CCl 2 .Me 



CHMe 2 .CH 2 .CHCl 2 ... 



CMe Cl . CMe.Cl 



C 6 H 12 C1 2 



j> 



C 7 H 14 C1 



Pra . CCl 2 . Prot 



C 8 H i6 Cl 2 



C 6 H" 3 .C0i 2 . Me .....'...! 



Melting- 



and 

 Boiling- 

 point. 



b. P . 

 b. P . 

 b. P . 

 b. P . 

 b. P . 

 b.p. 

 b. P . 

 b. P . 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b. P . 

 b. P . 



b.p. 

 b.p. 



m.p. 



b.p. 

 b. P . 



m.p. 



b.p. 

 b. P . 

 b.p. 

 b. P . 

 b. P . 

 b. P . 

 b. P 

 b.p. 

 b. P . 

 b.p. 

 b.p. 

 b. P . 



b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 bp. 

 b.p. 

 m.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 

 b.p. 



249 

 285 

 319 

 310 

 351 

 342 

 324 

 380 

 377 

 377 

 374 

 360 

 359 

 406 

 397 

 387 

 271 

 432 

 423 

 409 

 409 

 456 

 448 

 448 

 438 

 428 

 421 

 315 

 357 

 333 

 392 

 370 

 359 

 343 

 405 

 395 

 377 

 369 

 430 

 418 

 402 

 433 

 455 

 448 

 437 

 463 

 454 

 508 

 481 

 470 



Authority. 



Eegnault. 

 Linnemann. 



Perkin. 



Lieben and Eossi. 



Wagner and Saytzeff. 



Cariii3 and Fries. 



Butlerow. 



Perkin. 



Lieben and Janecek. 



Schorlemmer. 



Friedel and Silva. 



Kaschirsky. 



Cross. 



Butlerow. 

 Rohu. 

 Perkin. 

 Schorlemmer. 



Butlerow. 



Thorpe. 



Reboul. 



Linnemann. 



Reboul. 



Perkin. 



Wurtz. 



Kopp. 



CEconimides. 



Bnrylants. 



Buff. 



Eriedel. 



Bruylants. 



Friedel and Silva. 



Pelouze and Cahours. 



Wurtz. 



Henry. 



Schorlemmer. 



Tawildarow. 



Thorpe and Young. 



Nieson . 



Annalen, cvi. 271. 



