some Thermodynamical Relations 

 C 6 H 5 C1 



39 



7. Chlorobenzene and Water 

 taken as correct. c = '000598. 



H 2 



Temp, of water 



Pressures. 



Eatios. 



Absolute temperatures 

 of Chlorobenzene. 



From observed 

 temperatures. 



Smoothed. 



Eecalculated. 



Observed. 



millim. 

 100 

 150 

 200 

 300 

 400 

 500 

 600 

 700 



10579 

 10625 

 1-0654 

 1-0711 

 1-0753 

 1-0788 

 10819 

 1-0845 



1-0573 

 1-0623 

 1-0660 

 10716 

 1-0760 

 1-0791 

 1-0820 

 1-0845 



343-3 



353-85 



362-0 



373-9 



383-05 



390-3 



396-55 



402-0 



343-5 

 353-9 

 361-8 

 373-7 

 382-8 

 390-2 

 396-5 

 4020 



8. Bromobenzene and Water. 

 taken as correct. c = -000609. 



CoH 5 Br 

 H 2 ' 



Temp, of water 



Pressures. 



Eatios. 



Absolute temperatures 

 of Bromobenzene. 



From observed 

 temperatures. 



Smoothed. 



Eecalculated. 



Observed. 



millim. 



50 

 100 

 150 

 200 

 300 

 400 

 500 

 600 

 700 

 800 



1-1156 

 1-1220 

 11255 

 11284 

 1-1344 

 1-1388 

 1-1427 

 1-1460 

 1-1489 

 1-1516 



1-1124 

 1-1206 

 1-1258 

 M297 

 1-1353 

 1-1396 

 11431 

 1-1460 

 1-1486 

 1-1509 



3463 



363-9 



3750 



383-65 



396-1 



405-7 



413-45 



420-0 



425-8 



430-95 



347-3 

 3643 

 374-9 

 383-2 

 395-8 

 405-4 

 413-3 

 4200 

 425-9 

 431-2 



9. Aniline and Water. 

 as correct. c = "000345. 



C 6 H 5 NH, 

 H 2 



Temp, of water taken 



Pressures. 



Eatios. 



Absolute temp, of Aniline. 



From observed 

 temperatures. 



Smoothed. 



Eecalculated. 



Observed. 



millim. 

 50 

 100 

 150 

 200 

 300 

 400 

 500 

 600 

 700 

 800 



1-2046 

 1-2100 

 1-2129 

 1-2144 

 1-2174 

 1-2197 

 1-2217 

 1-2237 

 1-2254 

 1-2269 



1-2048 

 1-2094 

 1-2124 

 1-2145 

 1-2176 

 1-2201 

 1-2221 

 1-2239 

 1-2253 

 1-2266 



37505 



392-7 



403-85 



412-45 



424-8 



434-4 



4421 



448-55 



454-2 



459-3 



3750. 



392-9 



404-0 



412-4 



424-75 



434-2 



441-9 



448-5 



454-25 



459-4 



