Substituted Aliphatic Alcohols. 



3Y9 



Table 1. 

 Hydrolysis at 35° in decinormal hydrochloric acid. 



/^-hydroxy- /?-niethoxy- ^S-ethoxy- /5-chlor- /?-brom- 

 Ester ethyl ethyl ethyl ethyl ethyl 



acetate acetate acetate acetate acetate 



Time 





..2830 







3300 



2943 



2835 







f 46-2 





46-8 



47-4 



53-3 







47-4 





47-1 



46-5 



54-2 







47-1 





46-6 



46-3 



54-0 



K X 10^ 





{ 46-9 





46-2 



46-0 



55-4 







47-3 





46-1 



46-0 



55-8 







47-2 





46-5 



47-4 



56-0 







47-6 





45-5 



46-1 



56-9 



Averages 



47-1 



46-4 



46-5 



55-1 



Averages 





47-2 





46-6 



47-2 



56-5 



(duplicate) 















Hydr 



olysis at 35° 



in decinormal hydroc 



iloric acid. 





Time 





. . 660 



840 



870 



660 



660 







f (111-8) 



122-8 



117-8 



115-5 









115-6 



121-2 



117-3 



117-5 



(109-3) 







117-8 



119*6 



117-0 



118-4 



124-2 



K X 10^ 



< 



117-6 



122-3 



118-2 



118-2 



132-2 







117-9 



122-6 



1172 



117-4 



135-5 







117-2 



123-4 



117-5 



117-6 



139-7 







118-6 



123-7 



118-5 



118-6 



140-7 



Averages 



117-4 



122-2 



117-6 



117-6 



134-5 



Averages 





117-2 



122-8 



117-7 



117-6 



134-8 



(duplicate) 















Hydr 



olysis at 45° 



in decinormal hydrochloric acid. 





Time 





.. 210 



212 



213 



210 



210 







' (252) 



(259) 



(277) 



(252) 









280 



281 



279 



271 



(226) 







278 



281 



279 



272 



288 



K X 10^ 



. 



278 



280 



278 



273 



297 







278 



283 



279 



278 



298 







279 



283 



280 



277 



306 







280 



282 



280 



278 



300 



Averages 



279 



282 



279 



275 



298 



Averages 





279 



281 



280 



275 



297 



(duplicate) 













