Mercuric Chloride by Phosphorous Acid. 



363 



HgCl, 



H 3 PO, 



HC1 =0-] 



Table III (continued). 



0-132 gram mols per liter = a 



0-0575 " " " " = b T=60° 

 a a cc u Q 



x = HgCl 



55 

 107 

 148 

 198 



248 

 298 

 358 

 418 



<x 



in grams 

 0-1610 

 02746 

 0-3406 

 0-4060 

 0-4456 

 0-4754 

 0-4991 

 0-5144 

 0-5417 



in mols 



0-03418 



0-05830 



0-07231 



0-08620 



0-09461 



0-10093 



0-10597 



0-10921 



0-11500 



Ki* 



K,f 



0-479 



0-221 



0-536 



0-218 



0-536 



0-215 



0-620 



0-221 



0-671 



0-219 



0-741 



0-221 



0-833 



0-221 



0-923 



0-223 



* Calculated from Equation (6). f Calculated from Equation (11). 



Table IV. 



HgCl Q = 0*132 gram mols per liter = a 

 H 3 P0 3 = 0-0585 " " " « = b T 

 HC1 = 2-0 " " " " 



25-2' 



x = HgCl 



t 

 in hrs. 



5-1 

 8-3 

 10-0 

 13-1 

 15-5 

 23-8 

 31-0 

 a 



in grams 

 0-1446 

 0-2100 

 0-2392 

 0-2840 

 0-3104 

 0-3820 

 0-4198 

 0-5511 



in mols 



•0307 

 •0446 

 •0508 

 •0603 

 •0659 

 •0811 

 •0891 

 1170 



Ki* 



K 2 f 



0-518 



0*241 



0-543 



0-241 



0*557 



0-241 



0-580 



0-241 



0-587 



0-236 



0-629 



0-235 



0-728 



0-224 



* Calculated from Equation (4). f Calculated from Equation (12). 



0-132 gram mols per liter = a 



0-0585 " " " " = b T = 25-2° 



-] .a a a a a 



HgCl, 

 H.PO, 

 HC1 



t 

 in hrs. 



7-0 

 10-3 

 14-4 

 24-0 

 31-5 

 49-8 

 57-5 

 73-5 

 a 



x = HgCl 



m grams 

 0-1290 

 0-1760 

 0-2246 

 0-3130 

 0-3600 

 0-4342 

 0-4544 

 0-4830 

 0-5511 



in mols 

 0-0274 

 0-0374 

 0-0477 

 0-0665 

 0-0764 

 0-0922 

 0-0965 

 0-1026 

 0-1170 



Ki* 



Kif 



0-325 



0-153 



0-336 



0-153 



0-348 



0-153 



0-386 



0-156 



0-409 



0-155 



0-471 



0153 



0-500 



0-152 



0-538 



0-149 



* Calculated from Equation (4). f Calculated from Equation (12). 



