Mercuric Chloride by Phosphorous Acid. 



365 



Table IV (continued). 



HgCl 2 = 0-132 gram mols per liter = a 

 H 3 P0 3 = 0-059 " " " " = I 

 HC1 = 0-5 " " " " = C 



25-2' 



t 



in hrs. 



6'9 

 20-5 

 29-0 

 54'^ 

 94-0 

 148-0 



x = HgCl 



m grams 



0-0754 



0*1936 



0-2510 



0-3704 



0-4626 



0-5122 



0-5558 



in mols 



•01601 

 •04110 

 •05329 

 •07864 

 •09822 

 •10875 

 •11800 



0-336 

 0-367 

 0-388 

 0-458 

 0-563 

 0-664 



•163 

 •166 

 •167 

 •171 

 •170 

 •161 



* Calculated from Equation (6). \ Calculated from Equation (11). 



HoC] o = 0*132 gram mols per liter = a 

 H.PO", =0-059 " " " " =b T = 

 HC1 = 0-264 " " " " = C 



x = HgCl 



25'2 ( 



t 

 in hrs. 



in grams 



-a — 



in mols 



K,* 



K 2 f 



5-7 



0-0356 





0-00756 



0-339 



0-167 



26-3 



0-1500 





0-03185 



0-371 



0-173 



52-0 



0*2606 





0-05554 



0-417 



0-178 



73-7 



0-3322 





0-07053 



0-460 



0-183 



95-0 



0-3840 





0-08153 



0-504 



0-185 



1203 



0-4304 





0-09138 



0-563 



0-189 



141*6 



0-4582 





0-09728 



0-610 



0-189 



163-2 



0-4792 





0-10174 



0-656 



0-189 



214-0 



0-5110 





0-10849 



0-756 



0-187 



261-5 



0-5266 





0-11180 



0-809 



0-182 



a 



0*5558 





0-11800 







* Calculated from Equat 



ion 



(6). f Calculated from Equation ( 



HgCl, 



= 0-132 gi 



-am 



i mols per liter 



= a 





H 3 P0 3 



= 0-059 



ct 



it a a 



= b T 



= 25-2 



HC1 



= 0-132 



it 



u u a 



= C 





t 



in hrs. 



x - 



= H 



gCl 







in grams 





in mols 



Ki* 



K 9 f 



5-7 



0-0198 





0-00420 



0-366 



0-181 



26-5 



0-0884 





0-01877 



0-378 



0-181 



52-0 



0-1652 





0-03507 



0-398 



0-184 



78-2 



0-2350 





0-04989 



0-428 



0-188 



120-3 



0-3254 





0-06909 



0-478 



0-192 



163-0 



0-3940 





0-08365 



0-540 



0-197 



214-0 



0-4500 





0-09554 



0-627 



0-202 



261-3 



0-4838 





0-10272 



0-709 



0-204 



308-0 



0*5060 





0-10743 



0-789 



0-205 



a 



0-5558 





0-11800 







* Calculated from Equation (6). + Calculated from Equation (11). 



