366 



G. A. Linhart — Rate of the Reduction of 



HgCl, 

 H 3 P0 3 

 HC1 



Table V. 



0*132 gram mols per liter = a 



0-067 " " " " = b 

 j-q a a a a 



T = 25'2 C 



t 



in hrs. 



5-6 

 10-0 

 24-6 

 33-0 

 47'5 

 56-5 

 80-0 



00 



HgCl 



m grams 

 0-1186 

 0-1936 

 0-3558 

 0-4114 

 0-4752 

 0-5006 

 0*5414 

 0-6217 



in mols 

 0-0252 

 0-0411 

 0-0755 

 0-0837 

 0-1009 

 0-1063 

 0-1150 

 0-1320 



Ki* 



K 2 + 



0-314 



0-148 



0-337 



0-151 



0-401 



0-153 



0-435 



0-152 



0-500 



0-148 



0-530 



0-145 



0-600 



(0-134) 



^Calculated from Equation (4). f Calculated from Equation (12). 



HgCl 2 = 

 H s P0 3 = 0-067 

 HC1 = 0-5 



0.132 gram mols per liter = a 



a a a A 



it a a p 



T= 25'2 ( 



t 



in hrs. 



6-3 

 22-2 

 32-0 

 48-2 

 93-Y 

 141-0 

 oc 



:HgCl 



m grams 



0-0794 



0-2356 



0-3064 



0-3930 



0-5166 



0-5634 



0-6217 



in mols 

 0-01686 

 0-05000 

 0-06505 

 0-08344 

 0-10968 

 0-11962 

 0-13200 



0-342 

 0-388 

 0-417 

 0-474 

 0-650 

 0-799 



K 2 f 

 167 

 171 

 173 

 175 

 170 

 154) 



Calculated from Equation (6). f Calculated from Equation (11). 

 HgCl 2 = 0-132 gram mols per liter = a 



H 3 P0 3 



= 0-067 



a 



a a i 



' =zb T 



= 25-2° 



HOI 



= 0-264 



a 



a a a Q 







X - 



= HgCl 







t 

 in hrs. 





_A 





K,* 





in grams 





in mols 



K 2 f 



6-3 



0-0468 





0-00994 



0-359 



0-179 



22-4 



0-1512 





03210 



0-379 



0-180 



31-8 



0-2056 





0-04365 



0-401 



0-184 



48-2 



0-2860 





0-06072 



0-437 



0-189 



93-2 



0-4370 





0-09278 



0-570 



0-195 



194-0 



0-5614 





0-11920 



0-931 



0-196 



oc 



0-6217 





0-13200 







* Calculated from Equation (6). \ Calculated from Equation (11). 



