alliation: of datcylie. ae i iydroxybean te acids, 
rede y is 0.0. :p-triallylphenol, since the beats 
is. are” vai up, i eeisuk exception, dato: Shon dioxide or NE aad 
. The latter is prepared easier by rearrangement of 0, 0-diallylphenol allyl 
i ng ¢ on heating  Siallspkeng, in alcohol, with allyl Beers and potassium 
' OCH. CH, 
4 ae CH 
it ee 
‘ ee (il) Methyleumarane, 
pee EL 
ASH ‘a x 
Uae | . eae ag ee ¥ - ees Bia eae 
vy +i 5 Diallysaicyi acid. Ha: ae 0, ae ina Bort NOH 
Sse 1S: ee SEO Has : es (VI) p Nitseve-o-allyiphench brad 
ee  octy, 
Je yEOr: of ae CoH pe CH; " BS COsCH, cH.O a ~ COWCH, 
-* «vil Guatacsicarboxglic acid. a (Vill) Guaiacolearboxylic : (IX) Guaiascl poten 
ia an ie acid methyl ester. allyl ether methyl ester, 
I OH OM ae 
rere. .CO.CH,. | CHO” \\co.H (HO oo 
3 ' : : - é f > 4 \: : eS | ; j x 1 ar : 
Byer HCH. C3H; | ee Cables : 
Ss (x) p-Allylguaiacolcarbo- : (XI) p-Allylguaiacol- bs (XII) p-Eugenol. 
_ xylic acid methyl ester. . - carboxylic acid. . iat 
Diese ew or OH ate 
: (XIII) Ally! ether guaiacol- us (XIV) o-Eugenol. 
is es acid. 
3 rieaate on the water-bath; faintly- smelling liquid, b.p. 132.5 to_ 134° (11 aan: 
‘des 0.9548. When heating this ether in a current of COs, favourably with dimethyl- 
aniline, 0, 0 ,p-triallylphenol is formed, a colourless oil with a weak, persistent, rather 
unpleasant smell reminding somewhat of phosphines. B.p. 293 to 295° (760 mm); 
158 to 159° (14mm.); dze © 0.9785. Its acidity is very low, and in order to obtain a tolerably 
clear solution, 80 to 100 Potties! of standard potash solution are required, from which 
is extracts the phenol say eee Phenylurethane,. m. p. 97°. 
4 
wt 
re Pie 
