NARRATIVE OF THE ORITISE. 
1)77 
Believing that in whatever combination the carbonic acid might be present it would bo 
liberated by boiling the water with excess of acid, Mr. Buchanan proposed to determine 
the total carbonic acid by boiling the acidified water and determining the eliminated car- 
bonic acid. This method was met by the sufficient objection that the carbonic acid so 
determined would include any that might be present as neutral carbonate, that is, it would 
include both the molecules of carbonic acid of any bicarbonate which might be present. 
The sufficiency of this objection lies in the fact that in 1872 the object of determining 
the carbonic acid in the water was to furnish precise data as to the state of the 
atmospheric contents of the water or the amount to which the atmosphere available for 
the creatures living in the water was vitiated, and it was felt that the so-called half- 
bound carbonic acid of a bicarbonate might be considered as belonging to the atmosphere, 
but that this was impossible with the other and more closely combined portion. 
This being so, Mr. Buchanan lost no time in making such investigations as the short 
time available would admit of into what misfit be the cause of the retention of the 
carbonic acid. It was, of course, well knovui that if carbonates were present they would 
account for some portion of the retained carbonic acid, but in view of the negative 
results which had attended the labours of some chemists who had sought for them, it was 
evidently important to experiment on other ingredients known to be present in quantity 
in sea water, and of these the sulphates of lime and magnesia and the chlorides of 
magnesium and sodium claimed chief attention. 
Solutions of these salts were saturated with carbonic acid and distilled either imme- 
diately or after an interval of time, and it was found that, as compared with the 
behaviour of distilled water when similarly treated, solution of sulphate of magnesium 
exhibited the property of retaining carbonic acid in a marked way like sea water. This 
being so, Mr. Buchanan drew the practical conclusion that if the carbonic acid is 
retained whether in whole or in part by the sulphates it will be more easily extracted 
if these are eliminated. For this purpose, in all the determinations made on board 
the Challenger, a sufficient quantity (10 c.c.) of a saturated solution of chloride of 
barium was added to the sample before boiling. The immediately apparent effect of this 
was that the carbonic acid came away easily and abundantly the moment the water 
boiled, and passed principally in the first fifth of the distillate ; also the liquid boiled 
down to dryness without any bumping. 
As has been mentioned above, one great result of Tornqe’s work in connection with 
the Norwegian expedition was to show that in the waters examined by him the amount 
of carbonic acid present w T as insufficient to form bicarbonate with the neutral carbonate 
which he so easily and accurately estimates by his alkalinity method. It is probable that 
this holds in the majority of cases, so that the retention of the carbonic acid is accounted 
for by the dissolved carbonate without the necessity of calling in the assistance of the 
sulphates. How was it then that the precipitation of the sulphates as baryta sulphate 
